Belolipetsky and Jones classified those compact Riemann surfaces of genus g admitting a large group of automorphisms of order λ(g − 1), for each λ > 6, under the assumption that g − 1 is a prime number. In this article we study the remaining large cases; namely, we classify Riemann surfaces admitting 5(g − 1) and 6(g − 1) automorphisms, with g − 1 a prime number. As a consequence, we obtain the classification of Riemann surfaces admitting a group of automorphisms of order 3(g − 1), with g − 1 a prime number. We also provide isogeny decompositions of their Jacobian varieties.