Present study is on partial/complete coalescence dynamics of a droplet (surrounded by air) over a horizontal pool of the same liquid. Experimental and numerical studies are presented for both isopropanol and glycerol droplet of a constant diameter. Numerical study is presented in more detail for the isopropanol droplet to study the effect of diameter ($$D=0.035-6.7 mm$$
D
=
0.035
-
6.7
m
m
) and surface tension coefficient ($$\gamma =2-200 mN/m$$
γ
=
2
-
200
m
N
/
m
) on the coalescence dynamics. For partial coalescence of an isopropanol droplet and complete coalescence of a glycerol droplet, excellent agreement is demonstrated between our numerically and experimentally obtained interface dynamics; and a qualitative discussion on the mechanism of the partial and complete coalescence is presented. Three regimes of partial coalescence − viscous, inertio-capillary and gravity − proposed in the literature for a liquid-liquid system are presented here for the present liquid-air system while studying the effect of diameter of the isopropanol droplet. Probably for the first time in the literature, our numerical study presents a flow and vorticity dynamics based quantitativeevidence of the coalescence-mechanism, analogy with a freely vibrating Spring-Mass-Damper System, the gravity regime for a liquid-gas system, and the effect of surface tension coefficient $$\gamma$$
γ
based coalescence dynamics study. The associated novel $$\gamma$$
γ
based droplet coalescence regime map presents a critical Ohnesorge number $$Oh_{c}$$
O
h
c
and critical Bond number $$Bo_{c}$$
B
o
c
for a transition from partial to full coalescence; and such critical values are also presented for the transition under effect of the droplet diameter. The critical values based transition boundaries, obtained separately for the varying D and varying $$\gamma$$
γ
, are demonstrated to be in excellent agreement with a correlation reported in the literature.