We study the stationary Navier-Stokes system with no-slip boundary condition on polygonal domains. Near each non-convex vertex the solution is shown to have a unique decomposition by singular and regular parts. The singular part is defined by a linear combination of the corner singularity functions of the Stokes type and the regular part is shown to have the H 2 × H 1 -regularity. Precisely, near a non-convex vertex located at 0 0 , u p = 1 1 1 + 2 2 2 + u R p R , u R p R ∈ H s × H s−1 for s ∈ 2 + 1 2 , where i = r i i , i = r i −1 i with 1/2 < 1 < 2 < 1, is a smooth cutoff function, and i is the stress intensity factor. Hence the velocity vector is not Lipshitz continuous at non-convex vertices and the pressure value is infinite there. Also viscous stress tensor and vorticity values blow up near non-convex vertices.