On some characteristics of cathodic processes in nickel electrodeposition

Application of a Built-In Microscopic Antimony Electrode for Potentiometric Studies on Zinc-Nickel Co-Deposition

“…The slopes 45 AE 5 mV and 50 AE 3 mV were obtained for the CAM with diameter of 30 mm and 100 mm, respectively. These values of slopes were smaller then those reported in [1][2][3]. It may be explained by the influence of pretreatment conditions on a small active area of the CAM.…”

“…It is also known, that an antimony electrode can be used for both pH b and pH s measurements [1,2]. In particular, electrochemically deposited Sb-coatings have been used also for pH s studies [3].…”

Recent developments in the electrodeposition of nickel and some nickel-based alloys

“…The anion X ) has been variously assumed to be OH ) , SO 4 2) or Cl ) [11,12]. By comparing the experimentally determined kinetic parameters with those calculated for the various rate-determining steps and ranges of coverage, they deduced that if a reaction mechanism of the general type (1)-(3) applied in a Watts bath (consisting of NiSO 4 + NaCl + H 3 BO 3 ): (i) the anion X ) must be the chloride ion and (ii) the rate-determining step was reaction (2), i.e.…”

“…In the present paper, we review studies of the electrodeposition of nickel and nickel based alloys over the last two decades, which have built on the extensive pioneering work of DiBari, Evans, Bockris, Matulis, Heusler, Weil, and Ives and many others [2][3][4][5][6][7][8][9]. The aim is to highlight new, and interesting, developments in nickel electrodeposition research and applications, and to indicate important trends in the field.…”

Electrochemical methods for template-assisted synthesis of nanostructured materials

“…This effect is explained in some cases based on the hydroxide suppression mechanism (Matulis and Sližys, 1964;Fan and Piron, 1996;Bai and Hu, 2005).…”