High-resolution doubly differential cross-section measurements and calculations for quasifree electrons elastically scattered through 180°from ground-state He-and H-like boron ions are presented. The measurements, covering the entire (for B 3+ ) and (for B 4+ ) Rydberg series populated by resonant excitation, were performed by zero-degree Auger projectile electron spectroscopy of 3.91 MeV B 4+ and 3.08-7.48 MeV B 3+ ions in collisions with H 2 targets. The projectile energy dependence study is used to further investigate other background contributions such as direct electron capture, direct excitation, and nonresonant transfer excitation. R-matrix calculations, particularly sensitive at this large scattering angle to electron correlation, exchange, and interference effects, are found to be in excellent overall agreement within the electron scattering model.