Abstract-In this paper, a 4 × 4 indoor Multiple-Input MultipleOutput Ultra-Wideband (MIMO-UWB) measurement campaign in the 2-5 GHz bandwidth is presented. The main contribution of this work is the impact of radio-wave polarization as well as the effect of frequency dependence on the capacity of MIMO-UWB systems working in an office environment. To accomplish this, the capacity for different polarizations is analyzed under two different assumptions: constant or variable Signal-to-Noise Ratio.