On the Chemistry of Fluoroorgano Derivatives of Group 13 Elements. 1 The Reactions of Perfluoroiodoalkanes and Pentafluoroiodobenzene with Triethylindium - Synthesis and Characterization of In(C2H5)2(C6F5) · N(C2H5)3 and In(C2H5)2(i-C3F7) · N(C2H5)3 and Spectroscopic Evidence for Bis(3,3,4,4,4-pentafluorobutyl)indium Iodide

Choi, Zel-Ho; Tyrra, Wieland

doi:10.1002/(sici)1521-3749(1998120)624:12<2015::aid-zaac2015>3.0.co;2-f

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Cited by 4 publications

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Indium: Organometallic Chemistry

Banger

2005

Encyclopedia of Inorganic Chemistry

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An overview of the chemistry of organoindium compounds containing at least one InC bond over the last ten years is reported in detail. In particular, the synthesis, characterization, properties of homoleptic and heteroleptic organoindium derivatives, organoindium(0), (I), and (II) compounds, and in addition anionic compounds are also reported. Furthermore, the use of organoindium compounds for thin film, nanotechnology, and organic synthesis is discussed.

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Indium: Organometallic Chemistry

Banger

2005

Encyclopedia of Inorganic Chemistry

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Indium: Organometallic Chemistry

Banger

2005

Encyclopedia of Inorganic and Bioinorganic Chemistry

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Pentafluoroethylaluminates: A Combined Synthetic, Spectroscopic, and Structural Study

Bischoff

Riefer

Wirthensohn

et al. 2020

Chemistry A European J

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Salts of the tetrakis(pentafluoroethyl)aluminate anion [Al(C2F5)4]− were obtained from AlCl3 and LiC2F5. They were isolated with different counter‐cations and characterized by NMR and vibrational spectroscopy and mass spectrometry. Degradation of the [Al(C2F5)4]− ion was found to proceed via 1,2‐fluorine shifts and stepwise loss of CF(CF3) under formation of [(C2F5)4−nAlFn]− (n=1–4) as assessed by NMR spectroscopy and mass spectrometry and supported by results of DFT calculations. In addition, the [(C2F5)AlF3]− ion was structurally characterized.

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Cited by 4 publications

References 12 publications

Indium: Organometallic Chemistry

Indium: Organometallic Chemistry

Indium: Organometallic Chemistry

Pentafluoroethylaluminates: A Combined Synthetic, Spectroscopic, and Structural Study

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