Ions, protons and possibly a small flux of electrons and positrons are accelerated outward from the polar cap of a normal or millisecond pulsar whose rotational spin is antiparallel with its magnetic moment. The Langmuir modes of this relativistic plasma have several properties of significance for the origin of coherent radio emission. The characteristics of the mode are determined by the sequence of singularities in the dielectric tensor at real angular frequencies, which in turn is fixed by the electronpositron momentum distribution. We find that under a certain condition on its momentum distribution, an electron-positron flux two orders of magnitude smaller than the Goldreich-Julian flux stabilizes the plasma and extinguishes the mode. But more generally, both the growth rate and wavenumber of the multi-component Langmuir mode can be as much as an order of magnitude larger than those of the two-component ion-proton mode. It appears to be a further effective source for the plasma turbulence whose decay is probably responsible for the observed emission.