1972
DOI: 10.3891/acta.chem.scand.26-0733
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On the Complex Formation Equilibria Between Indium(III) and Chloride Ions.

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Cited by 21 publications
(6 citation statements)
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“…However, Cl − ions can form relatively stable complexes with In 3+ ion with log β 1 , log β 2 and log β 3 values of 2.58, 3.84 and 4.20, respectively (25 °C, I = 3.0 M NaClO 4 ). (38) If the formation of InCl x (3−x)+ species is not taken into account, then the resulting stability constants only represent the lower limits of stability and the actual stability constants are somewhat higher (with about 4 log K units). This appears to be the case for In(DOTA), as its stability was measured in the presence of 0.1M KCl and the formation of InCl x (3−x)+ species was ignored by Clarke et al(36), whereas it was accounted for in the calculated stabilities of In(PCTA) and In(NO 2 -Bn-PCTA) here.…”
Section: Resultsmentioning
confidence: 99%
“…However, Cl − ions can form relatively stable complexes with In 3+ ion with log β 1 , log β 2 and log β 3 values of 2.58, 3.84 and 4.20, respectively (25 °C, I = 3.0 M NaClO 4 ). (38) If the formation of InCl x (3−x)+ species is not taken into account, then the resulting stability constants only represent the lower limits of stability and the actual stability constants are somewhat higher (with about 4 log K units). This appears to be the case for In(DOTA), as its stability was measured in the presence of 0.1M KCl and the formation of InCl x (3−x)+ species was ignored by Clarke et al(36), whereas it was accounted for in the calculated stabilities of In(PCTA) and In(NO 2 -Bn-PCTA) here.…”
Section: Resultsmentioning
confidence: 99%
“…In 3+ + 3H ), 44 whose cumulative stability constants are 10 2.58 , 10 3.84 and 10 4.2 , respectively. Cumulative stability constants 45 of ZnCl + , ZnCl 2 , ZnCl 3 2 , ZnCl 4 22 are 10 0.43 , 10 0.63 , 10 0.53 and 10 0.2 , respectively.…”
Section: Mechanismmentioning
confidence: 99%
“…), 35 whose cumulative stability constants are 10 2.58 , 10 3.84 and 10 4.2 , respectively. The reaction can be expressed as follows.…”
Section: Mechanismmentioning
confidence: 99%