On the coordination behaviour of diorganoselenium ligands based on amino and azole functionalities: silver(i) complexes with relevance for biological applications

Abstract

A series of novel silver(I) complexes of type [Ag(OTf)L] (L = RR'Se), namely [Ag(OTf)Se{C6H4(CH2NMe2)-2}(CH2Phtz)] (1), [Ag(OTf)Se{C6H4(CH2NEt2)-2}(CH2Phtz)] (2), [Ag(OTf)Se{C6H4[CH2N(CH2CH2)2O]-2}(CH2Phtz)] (3), [Ag(OTf)Se{C6H4(CH2NMe2)-2}(CH2CH2pz)] (4), [Ag(OTf)Se{C6H4(CH2NEt2)-2}(CH2CH2pz)] (5), [Ag(OTf)Se{C6H4[CH2N(CH2CH2)2O]-2}(CH2CH2pz)] (6), [Ag(OTf)Se(CH2Phtz)2] (7) were obtained by...