On the crystal structure of KInS2-I

Lowe-Ma, Charlotte K.; Kipp, D. O.; Vanderah, Terrell A.

doi:10.1016/0022-4596(91)90358-o

Cited by 16 publications

(14 citation statements)

References 14 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…2). Each In(1) atom is coordinated by S(1), S(3), S(4), S(5) atoms, each In(2) atom is coordinated by The coordination polyhedra of Cs(1) and Cs (2) in CsInS 2 can be described as bicapped trigonal prisms (Fig. 3).…”

Section: Structure Description and Observed Band Gapsmentioning

confidence: 99%

“…Many sulfide materials have transmission windows ranging from 0.5 to 14 m [1]. Multinary metal sulfides are optical ceramic materials [2,3] with potential applications. In our effort to search for this type of materials [4,5], single crystals of RbInS 2 and CsInS 2 of high quality were obtained through the traditional flux method [6].…”

Section: Introductionmentioning

confidence: 99%

“…In our effort to search for this type of materials [4,5], single crystals of RbInS 2 and CsInS 2 of high quality were obtained through the traditional flux method [6]. Although the X-ray powder data have been reported in literature [7], showing that RbInS 2 , CsInS 2 are isostructural with KInS 2 [8], KInS 2 -I [2], KInSe 2 [9] and TlGaSe 2 [10]. Recently, Huang et al [11] reported the preparation, structures and calculated band gaps of RbInS 2 and RbInSe 2 .…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Reactive flux syntheses, crystal structures and band gaps of AInS2 (A=Rb, Cs)

Zeng

Zheng

Chen

et al. 2007

Journal of Alloys and Compounds

View full text Add to dashboard Cite

Section: Structure Description and Observed Band Gapsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Reactive flux syntheses, crystal structures and band gaps of AInS2 (A=Rb, Cs)

Zeng

Zheng

Chen

et al. 2007

Journal of Alloys and Compounds

View full text Add to dashboard Cite

“…The coordination number of the In center in chalcogenides also varies. It is often four (LiInTe 2 [3], NaInTe 2 , KInTe 2 [4], and KInS 2 , [5]), but six is also common (NaInS 2 and NaInSe 2 [6]). The composition and coordination versatility play important roles in the structural diversity of the A/In/Q family.…”

Section: Introductionmentioning

confidence: 99%

Preparation, structures, and band gaps of RbInS2 and RbInSe2

Huang¹,

Deng²,

Ellis³

et al. 2005

Journal of Solid State Chemistry

View full text Add to dashboard Cite

“…Man kann daher erwarten, dass fu È r diese Kationen isotype Verbindungsreihen existieren. In der Tat entsprechen KInS 2 /RbInS 2 /CsInS 2 [15,16] (alle TlGaSe 2 -Typ) und KIn 5 S 8 /RbIn 5 S 8 /CsIn 5 S 8 (alle KIn 5 S 8 -Typ, [17]) jeweils diesem Schema. Versuche, ausgehend von KIn 5 S 6 und KIn 5 S 7 isotype Rubidium-und Caesium-Verbindungen zu synthetisieren, blieben unter den gewa È hlten Bedingungen jedoch bislang erfolglos.…”

unclassified

Die neuen gemischtvalenten Chalkogenoindate MIn7X9 (M = Rb, Cs; X = S, Se): Strukturchemie, Röntgenund HRTEM-Untersuchungen

Reiner

Deiseroth

Schlösser

et al. 2002

Z. anorg. allg. Chem.

View full text Add to dashboard Cite

Professor Hans Georg von Schnering zum 70. Geburtstag gewidmet Inhaltsu È bersicht. Systematische Ro È ntgen-und HRTEMUntersuchungen in den Dreistoffsystemen Alkalimetall (oder Thallium)±Indium±Chalkogen zeigen, dass eine Reihe von gemischtvalenten Verbindungen existiert, in denen Indium gleichzeitig in zwei Oxidationsstufen auftritt. Zusa È tzlich zu den bereits fru È her beschriebenen Verbindungen MIn 5 S 7 (M: Na, K, Tl: isotyp zu InIn 5 S 7 = In 6 S 7 und TlIn 5 S 7 ) und KIn 5 S 6 (isotyp zu TlIn 5 S 6 ) wird in dieser Arbeit mit MIn 7 X 9 (M: Rb, Cs; X: S, Se) ein neuer Strukturtyp vorgestellt, in dem ± ebenso wie in den beiden erstgenannten ± Indium in den Oxidationsstufen +3 und +2 auftritt. Dabei liegen die In-Spezies in der Oxidationsstufe +2 in Form von (In 2 ) 4+ -Ionen vor. Die Grenzformeln dieser Strukturtypen lassen sich mit Ionen wie folgt beschreiben: MIn 5 S 7 = M + 3[In 3+ ] [(In 2 ) 4+ ] 7[S 2± ] (M = Na, K, Tl), MIn 5 S 6 = M + [In 3+ ] 2[(In 2 ) 4+ ] 6[S 2± ] (M = K, Tl), MIn 7 X 9 = M + 3[In 3+ ] 2[(In 2 ) 4+ ] 9[S 2± ].Die drei Strukturtypen weisen gemeinsame zweidimensionale Strukturelemente auf, welche aus ethananalogen In 2 X 6 -Einheiten sowie cis-und transkantenverknu È pften Doppeloktaederketten bestehen. Im Vordergrund dieser Arbeit steht eine vergleichende kristallchemische Diskussion unter besonderer Beru È cksichtigung der neuen Phasen MIn 7 X 9 sowie spezielle HRTEM-Untersuchungen an Proben dieser Verbindungen. Letztere haben das vorrangige Ziel, neue Phasen, die zuna È chst nur als Nanokristalle im TEM sichtbar sind, zu identifizieren und anschlieûend in makroskopischen Mengen darzustellen.

show abstract

On the crystal structure of KInS2-I

Cited by 16 publications

References 14 publications

Reactive flux syntheses, crystal structures and band gaps of AInS2 (A=Rb, Cs)

Reactive flux syntheses, crystal structures and band gaps of AInS2 (A=Rb, Cs)

Preparation, structures, and band gaps of RbInS2 and RbInSe2

Die neuen gemischtvalenten Chalkogenoindate MIn7X9 (M = Rb, Cs; X = S, Se): Strukturchemie, Röntgenund HRTEM-Untersuchungen

Contact Info

Product

Resources

About