This article presents the results of tests carried out to assess the condition of PP-modified concrete. The tests were carried out on samples previously stored at ambient temperature and exposed to temperatures corresponding to fire conditions—300 °C, 450 °C, and 600 °C. Axial compression tests of cube-shaped samples and three-point bending of beams were carried out. During strength tests, acoustic emission (AE) signals were recorded and the force and deformation were measured. Recorded AE events were clustered using the k-means algorithm. The analysis of the test results allowed for the identification of signals characteristic of the individual stages of the material destruction process. Differences in the methods of destruction of samples stored in ambient conditions and those exposed to fire temperatures were also indicated. While loading the samples, measurements were carried out using the digital image correlation (DIC) method, which enabled the determination of displacements. Based on the results of the laboratory tests, a numerical model was developed. The results obtained using different research methods (DIC and FEM) were compared. Tomographic examinations and observations of the microstructure of the tested materials were also carried out. The analyses carried out allowed for a reliable assessment of the possibility of using the acoustic emission method to detect destructive processes and assess the technical condition of PP-modified concrete. It was confirmed that the acoustic emission method, due to differences at low load levels, can be a useful technique for assessing the condition of PP-modified concrete after exposure to fire temperatures. So far, no research directions in a similar field have been identified.