Reservoir conformance
control methods may significantly improve
enhanced oil recovery technologies through reduced water production
and profile correction. Excessive water production in oil and gas
reservoirs leads to severe problems. Water shutoff and conformance
control are, therefore, financially and environmentally advantageous
for the petroleum industry. In this paper, water shutoff performance
of citric acid-coated magnetite (CACM) and hematite nanoparticles
(NPs) as well as polyacrylamide polymer solution in a heterogeneous
and homogeneous two-dimensional micromodel is compared. A facile one-step
technique is used to synthesize the CACM NPs. The NPs, which are reusable,
easily prepared, and environmentally friendly, are characterized using
Fourier-transform infrared spectroscopy, field emission scanning electron
microscopy, dynamic light scattering, and X-ray diffraction. The results
confirm uniform spherical Fe
3
O
4
NPs of an average
diameter of 40 nm, well coated with citric acid. CACM NPs provide
a high pressure drop coupled with an acceptable resistance factor
and residual resistance factor owing to NP arrangement into a solid-/gel-like
structure in the presence of a magnetic field. A resistance factor
and a residual resistance factor of 3.5 and 2.14, respectively, were
achieved for heavy oil and the heterogeneous micromodel. This structure
contributed to an appreciable plugging efficiency. CACM NPs respond
to ∼1000 G of magnetic field intensity and display a constant
resistance factor at intensities between 4500 and 6000 G. CACM NPs
act as a gel, forming a solid-/gel-like structure, which moves toward
the magnetic field and thereby shuts off the produced water and increases
the oil fraction. The findings of this study suggest the ability to
shut off water production using specially designed magnetic field-responsive
smart fluids. The application would require innovative design of field
equipment.