In order to allow the advanced interpretation of the X-ray spectra registered by the high-resolution crystal KX1 spectrometer on the JET with an ITER-like wall, especially to determine how the relative emission contributions of tungsten and molybdenum ions change during a JET discharge, the X-ray spectra have been carefully modeled over a narrow wavelength range. The simulations have been done in the framework of Collisional-Radiative model implemented in Flexible Atomic Code for an electron density (n e = 2.5 9 10 19 m -3 ), and electron temperatures between T e = 3.0 keV and T e = 4.5 keV, typical for JET. Moreover, performed detailed analysis in the framework of the proposed procedure can be useful in determining temperature of a high temperature plasma generated in tokamaks.Keywords X-ray spectra Á Tokamak Á Tungsten M X-ray lines Á Molybdenum L X-ray lines Á High-resolution crystal spectrometer Journal of Fusion Energy https://doi.org/10.1007/s10894-020-00231-y( 0123456789().,-volV) (0123456789().,-volV)