“…13 However, an increase of the corresponding Mn II -Mn II distance from 2.974 to 3.057 Å after structure relaxation leads to the change from AFM to FM J 3 parameter, while the rest of the parameters are left almost unchanged. As a result the estimated value of the T C = 400 K for the relaxed Mn 5 Ge 3 system is somewhat higher than for the rigid one of 320 K and than the corresponding experimentally observed value of 304 K. 2 ϩThe results presented in Table II show that interstitial carbon, even without relaxation, significantly changes the value of J 2 , J 3 , and J 6 , leaving the J 4 and J 1 interactions almost unaffected. In particular, the J 3 interaction becomes strongly FM compared to the undoped Mn 5 Ge 3 .…”