In this paper, we study constraint minimizers of the following L 2 −critical minimization problem:and N denotes the mass of the particles in the Schrödinger-Poisson-Slater system. We prove that e(N) admits minimizers for N < N * ∶= ||Q|| 2 2 and, however, no minimizers for N > N * , where Q(x) is the unique positive solution of △u − u + u 7 3 = 0 in R 3 . Some results on the existence and nonexistence of minimizers for e(N * ) are also established. Further, when e(N * ) does not admit minimizers, the limit behavior of minimizers as N ↗ N * is also analyzed rigorously. KEYWORDS constraint minimizers, limit behavior, Schrödinger-Poisson-Slater system 4 3 u. From the physical point of view, we are interested in looking for solutions of Equation 1 with a prescribed L 2 -norm. Specifically, for any given constant N > 0, we look for solutions u N ∈ H 1 (R 3 ) with ||u N || 2 2 = N. Motivated by other studies, 8,14-16 taking N ∈ R in Equation 1 as a suitable Lagrange multiplier, a solution u N ∈ H 1 (R 3 ) of (1) Math Meth Appl Sci. 2017;40 7705-7721.wileyonlinelibrary.com/journal/mma