On the mechanism of propylene epoxidation catalyzed by molybdenum naphthenate

Sümegi, L.; Hajdú, István; Nemes, I.; Gedra, A.

doi:10.1007/bf02071425

Cited by 4 publications

(2 citation statements)

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“…We made an attempt to propose such a mechanism, which if used for different catalysts and hydroperoxides, describes the kinetics of the process being in good agreement with experimental data [1,2].…”

Section: Introductionmentioning

confidence: 65%

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On the kinetics of the transition metal catalyzed decomposition of secondary hydroperoxides

Hajdú

Nemes

Sümegi

et al. 1981

Int J of Chemical Kinetics

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A general mechanism was proposed for the title reactions which describes the kinetics of hydroperoxide decomposition as well as product accumulation throughout the whole reaction period in an analytical form. The following catalytic steps were included:where the deactivation takes place as a result of radical-catalyst interaction inside the cage. The resulting equations give satisfactory description of the literature data in the case of various catalysts and hydroperoxides.

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Section: Introductionmentioning

confidence: 65%

“…In certain cases alcohol [ll,l2] and water [12] did not affect the decomposition catalyzed by molybdenum naphthenate. Consequently the inhibiting effect of products should not be regarded the main reason for the deactivation process.…”

Section: Mechanism Of the Formation Of Ketonementioning

confidence: 99%