In this paper the classification of left-invariant Riemannian metrics, up to the action of the automorphism group, on cotangent bundle of (2n+1)-dimensional Heisenberg group is presented. Also, it is proved that the complex structure on that group is unique and the corresponding pseudo-Kähler metrics are described and shown to be Ricci flat. It is well known that this algebra admits an ad-invariant metric of neutral signature. Here, the uniqueness of such metric is proved.