Let T be a neutral Tannakian category over a field of characteristic zero with unit object ½, and equipped with a filtration W• similar to the weight filtration on mixed motives. Let M be an object of T, and u(M ) ⊂ W−1Hom(M, M ) the Lie algebra of the kernel of the natural surjection from the fundamental group of M to the fundamental group of Gr W M . A result of Deligne gives a characterization of u(M ) in terms of the extensions 0) such that the sum of the aforementioned extensions, considered as extensions of ½ by W−1Hom(M, M ), is the pushforward of an extension of ½ by u(M ). In this article, we study each of the above-mentioned extensions individually in relation to u(M ). Among other things, we obtain a refinement of Deligne's result, where we give a sufficient condition for when an individual extension 0 −→ WpM −→ M −→ M/WpM −→ 0 is the pushforward of an extension of ½ by u(M ). In the second half of the paper, we give an application to mixed motives whose unipotent radical of the motivic Galois group is as large as possible (i.e. with u(M ) = W−1Hom(M, M )). Using Grothedieck's formalism of extensions panachées we prove a classification result for such motives. Specializing to the category of mixed Tate motives we obtain a classification result for 3-dimensional mixed Tate motives over Q with three weights and large unipotent radicals.