2D materials currently includes graphene, transition metal dichalcogenides (TMDs), hexagonal boron nitride (h-BN), 2D carbides/nitrides (MXenes), monoelemental Xenes, and perovskites. [2][3][4][5][6] These families opened new horizons for advanced applications since they have unusual electronic, mechanical, and optical properties. Though these materials have layered structures, yet their diversity in properties highly depends on their composition and phases.Graphene owns interesting properties like large surface area, dangling bond-free surface, high carrier mobility, high optical absorption coefficient, high Young's modulus, and high thermal conductivity. [7] However, the zero bandgap and semimetal properties of graphene limit its application in switching devices. h-BN attracted magnetized attention due to its superb chemical stability and intrinsic insulation. [8] As one of the most studied families, TMDs offer diversity in compositions, and phases, which exhibit many technologically interesting properties. [9][10][11] Among TMDs, MoS 2 is the most examined and well-explored material due to its robustness and semiconducting properties. TMDs offer a unique combination of atomic-scale thickness, strong spin-orbit coupling, sizeable bandgap, and favorable optoelectronic properties for numerous applications. [12] MXenes represent a large family of 2D materials whose several structures were predicted theoretically, while several of them have been realized experimentally also such as Ti