On the prediction of Gibbs free energy of mixing of binary liquid alloys

Arzpeyma, Gilnaz; Gheribi, Aïmen E.; Medraj, Mamoun

doi:10.1016/j.jct.2012.07.020

Cited by 27 publications

(8 citation statements)

References 56 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The dissolution of monomeric compounds tends to be strongly favored by an increase in entropy of the system (Arzpeyma et al 2013). In other words, the system becomes more random when two different pure substances become intimately mixed.…”

Section: Solubility Parametersmentioning

confidence: 99%

Hydrophobic copolymers added with starch at the size press of a paper machine: A review of findings and likely mechanisms

Dal

Hubbe

2020

BioRes

View full text Add to dashboard Cite

This article reviews publications with the goal of understanding the role of hydrophobic copolymers added to size-press starch as a means to make paper products more resistant to penetration by aqueous fluids. The underlying technology is considered, including background related to starch, size-press equipment, and various hydrophobic copolymers and latex products that have been evaluated. The resulting hydrophobization of the paper has been reported to depend not only on the dosage of the hydrophobic additive, but also on its molecular mass and ionic form. The mechanism appears to rely on an ability of starch to serve as a temporary host for hydrophobic compounds in aqueous solution. It has been proposed that hydrophobic copolymers added with size press starch tend to migrate to the air interface during drying of the starch film, thus allowing the low-energy functional groups, such as styrene or alkyl chains, to face outwards. Further research is needed to address various mechanistic questions. There may be opportunities to further raise the performance of this type of technology as practiced within paper production factories.

show abstract

Section: Solubility Parametersmentioning

confidence: 99%

Hydrophobic copolymers added with starch at the size press of a paper machine: A review of findings and likely mechanisms

Dal

Hubbe

2020

BioRes

View full text Add to dashboard Cite

show abstract

“…The denominator, Z, called the partition function, is figured out so about make the amount of probabilities of all states of the system (i.e., the probability that the system remains in some state) equivalent to one [5][6][7]. the gibbs free energy: The change in Gibbs free energy in between two various chemical substances (compounds or conformations) that identifies the position of the balance between these states [8][9][10][11]. We signify the Gibbs free energy change for any procedure as △ .…”

Section: S= K Log W (1)mentioning

confidence: 99%

Showing Relationship in Between a Same Reaction in both Liquid and Gas Phase by Monatomic Oxidation Hypothesis

2019

International Journal of Research Studies in Microbiology and B

View full text Add to dashboard Cite

The new hypothesis based on "heat of a reaction which occurs in both the gas system, and the liquid system should be equal". In the early 19th century, William Henry stated that the concentration of the gas in the "gas system" would be directly proportional to its concentration in the "liquid system" at the constant temperature. However, Henry's law coefficient mainly varies with the temperature of the scheme. Also, Gustav Kirchoff described the "heat capacity", which is equal to change in enthalpy-introduced by Josiah Willard Gibbs in 1870's, then first called "enthalpy" in J. P. Dalton's scientific paper, in 1909-divided by the change in temperature, at constant pressure, in 1858's. This inference is based on the mathematical expression of the single atomic hypothesis. This hypothesis is often derived from a reaction that produces the same product output in two different systems to explain the ongoing events with each other. For example, in order for a coal particle to burn well, it is also important to cause the coal particle to ignite earlier during combustion, which is also an oxidation reaction, due to the oxidation reaction in water.

show abstract

“…Gibbs free energy (G) is an important parameter in thermodynamics 20,21 , which has the properties of a state function, that is, Gibbs free energy change (ΔG) is determined by the initial and the final state, and has nothing to do with the path of change.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic performance judgment of organic Rankine cycle based on Gibbs free energy change

Xinfeng

et al. 2022

Preprint

View full text Add to dashboard Cite

Since Gibbs free energy change (ΔG) can judge the maximum ability of the system to do other useful work besides expansion work, ∆G was introduced into the general thermodynamic model of the ORC, the relationships between work, heat, exergy and ∆G were derived to judge the thermodynamic performance of ORC. And the ORC using pure fluid of R245fa and zeotropic mixture of R245fa/R227ea were selected as the study cases, analyzed the influence of different evaporation pressures, condensation pressures, heat source outlet temperatures and mass fractions of R245fa on the ∆G of the four thermodynamic processes to judge the ORC thermodynamic performances, the judgment results were compared with the calculation results. The results indicate that the change trends of net output power, thermal and exergy efficiencies judged by the ΔG are consistent with calculation results. The ability of ORC to do work increases with increase of Gibbs free energy change of heat absorption process (∆Ge), but the evaporator exergy destruction is affected by ∆Ge and working fluid entropy increase, its change depends on the specific working conditions; Output power is improved with increase of Gibbs free energy change of expansion process (∆Gt), but it will increase the turbine exergy destruction.

show abstract

On the prediction of Gibbs free energy of mixing of binary liquid alloys

Cited by 27 publications

References 56 publications

Hydrophobic copolymers added with starch at the size press of a paper machine: A review of findings and likely mechanisms

Hydrophobic copolymers added with starch at the size press of a paper machine: A review of findings and likely mechanisms

Showing Relationship in Between a Same Reaction in both Liquid and Gas Phase by Monatomic Oxidation Hypothesis

Thermodynamic performance judgment of organic Rankine cycle based on Gibbs free energy change

Contact Info

Product

Resources

About