This work explores the heterogeneous effect of urbanization and nonrenewable energy consumption on the environment in 54 African nations. Panel data were used from 1996 to 2019. For estimation, panel quantile regression analysis, augmented mean group, panel threshold regression, and the environment Kuznets curve hypothesis were applied to check the relationship between income and carbon emissions. The study's outcome demonstrates that urbanization and nonrenewable energy consumption degrade the environment in Africa. Furthermore, an inverted U‐shape relationship exists between economic growth and CO2 emissions, confirming the environmental Kuznets curve hypothesis. The findings indicate that urbanization should be planned; otherwise, urbanization can cause environmental degradation. African countries must adopt green urbanization and use renewable energy and clean manufacturing technologies. The institutions are encouraged to execute the standard, regulatory environment, and policies to reduce carbon emissions. Countries throughout the African continent should actively respond to the issues by charting a separate and diverse route for urban development.