On the role charge ordering in the dynamics of cluster formation in associated liquids

Abstract

Liquids are archetypes of disordered systems, yet liquids of polar molecules are locally more ordered than non-polar molecules, due to the Coulomb interaction based charge ordering phenomenon. Hydrogen bonded liquids, such as water or alcohols, for example, represent a special type of polar liquids, in that they form labile clustered local structures. For water, in particular, hydrogen bonding and the related local tetrahedrality, play an important role in the various attempts to understand this liquid. However, labile structures imply dynamics, and it is not clear how it affects the understanding of this type of liquids from purely static point of view. Herein, we propose to reconsider hydrogen bonding as a charge ordering process. This perspective allows to demonstrate the insufficiencies of the analysis of the microscopic structure based solely on static pair correlation functions, and the need for dynamical correlation functions, both in real and reciprocal space. This extended analysis allows to recover several aspects of our understanding of hydrogen bonded liquids, but from a unified viewpoint. For water, it confirms the jump rotation picture found recently, and it allows to rationalize the contradicting pictures that arise when following the interpretations based on hydrogen bonding. For alcohols, it allows to understand the dynamical origin of the scattering pre-peak, which does not exist for water, despite the fact that both these liquids have very similar hydroxyl group chain clusters. The concept of charge ordering complemented by the analysis of dynamical correlation functions appear as a promising way to understand micro-heterogeneity in complex liquids and mixtures from kinetics point of view

Speciation and organic phase structure in nitric acid extraction with trioctylamine

“…Hydrogen bonding networks have been found to be particularly important in nanoscale structuring, [39][40][41] but in the presence of charged species other interactions can also be significant. [42][43][44][45] Aggregation of amine and ammonium-based extractants has been related to metal extraction and separation trends. 16,46,47 This aggregation phenomenon has been principally studied using X-ray and neutron scattering techniques and the data fit to colloidal models, wherein the polar and non-polar species in the organic phase self-assemble into reverse-micellar structures.…”

Speciation and organic phase structure in nitric acid extraction with trioctylamine

“…Hydrogen bonding networks have been found to be particularly important in nanoscale structuring, [47][48][49] but in the presence of charged species other interactions can also be significant. [50][51][52][53] Aggregation of amine and ammonium-based extractants has been related to metal extraction and separation trends. 12,54,55 This aggregation phenomenon has been principally studied using X-ray and neutron scattering techniques and the data fit to colloidal models, wherein the polar and non-polar species in the organic phase self-assemble into reverse-micellar structures.…”

Reply to the ‘Comment on “Universal features in the lifetime distribution of clusters in hydrogen-bonding liquids”’ by J. Grelska, Phys. Chem. Chem. Phys., 2024, 26, https://doi.org/10.1039/D3CP05269A

“…1, which ignore molecular details, and which are part of usual theoretical framework on the kinetics of clustering. 10 The requirement of having a theory which incorporates the microscopic kinetics through the dynamical van Hove correlation function G OO (r,t), with molecular details, is quite challenging, 11,12 and is currently being pursued.…”