On the Role of the Orbital Interaction Concept in the Interpretation of Organic Free Radical Structures and Reactivities

Thermochemical unification of molecular descriptors to predict radical hydrogen abstraction with low computational cost

“…8); the reactivity sequence (Tables T2-T4, ESI †) is in line with previous studies. [54][55][56][57] E SOMO relates to electron accepting/donating ability, electrophilicity (S5, ESI †) 54 and 'electron affinity', e x ( Fig. 8 and Fig.…”