Abstract:A faradaic impedance study has been made of the reduction of Cd(II) ions from a 1 M KF base electrolyte at the DME. It could be shown that only the Cd(II) present in the solution and the end product, viz. Cd(Hg), are the diffusing partmles and that intermediates are present only at the interface. From the analysis of the impedance data it followed that at the interface the Cd(II) species is first subject to a heterogeneous chemical transfer and thereafter is reduced according to two discrete one-electron trans… Show more
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