On the stability and decomposition of phenyl (phenylazo) methyl hydroperoxide

Vágó, Júlia; Paál‐Lukács, J.

doi:10.1016/s0040-4039(00)76194-6

Cited by 7 publications

(1 citation statement)

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“…Peroxy compounds such as hydrogen peroxide, organic hydroperoxides, peracids and ozone are well known sources of active oxygen and have been used for the oxidation of sulfides to sulfoxides. Among organic hydroperoxides, urea-hydrogen peroxide (UHP) [77], tert-butyl hydroperoxide (TBHP) [78], 2hydroperoxyhexafluoro-2-propanol [79], flavin hydroperoxide [80] and α-azohydroperoxide [81] are well documented as oxidants for sulfoxidation. In 1928 Lewin reported the use of perbenzoic acid for sulfoxidation of sulfides at room temperature [82] while Sakuraba et al reported the use of peracetic acid for the same oxidation [83].…”

Section: Peroxides Peracids and Ozonementioning

confidence: 99%

A Concise Review on Synthesis of Sulfoxides and Sulfones with Special Reference to Oxidation of Sulfides

Kupwade

2019

J. Chem. Rev.

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A large variety of organosulfur compounds have been shown to having diverse biological effects such as antioxidant effects, anti-inflammatory properties, inhibition of platelet aggregation, reduction of systolic blood pressure, and reduction of cholesterol. Among these, sulfoxides and sulfones show wide and significant applications as commodity chemical in various fields of chemistry. Therefore, synthesis of sulfoxides as well as sulfones has remained a point of attraction for synthetic organic chemists. Among array of methods used to synthesize the sulfoxides or sulfones, oxidation of sulfide is the most convenient way. This review precises chemoselective methods for the synthesis of the sulfoxides as well as sulfones focusing on oxidative protocols. This review will aid researchers to explore and utilise the mentioned protocols for different organic transformations.

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