On the synthesis of methacryloyloxyacetic acid

Guistina, R. A.; Hall, H. K.

doi:10.1007/bf00338901

Cited by 1 publication

(2 citation statements)

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“…Two new methacrylic monomers bearing a carboxyl group spaced apart from the double bond, 6-methacryloyloxyhexanoic (AMOE) and 6-(N-methacryloyl)aminohexanoic (AMAE) acids, were prepared by a modification of the synthesis of methacryloyloxyacetic acid [25].…”

Section: Monomer Synthesismentioning

confidence: 99%

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Synthesis and Characterization of New Functional Polyelectrolytes Based on Carboxyl Containing Methacrylates

Tamburro¹,

Chiellini²,

Solaro³

2001

Journal of Bioactive and Compatible Polymers

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Three new methacrylic monomers, 6-methacryloyloxyhexanoic acid, 6-(N-methacryloyl)aminohexanoic acid, and ethyl 6-(N-methacryloyl)-aminohexanoate, containing carboxyl groups spaced from the polymerizable double bond by a polymethylene chain, have been synthesized. Multifunctional polymeric materials were obtained by radical polymerization of these monomers with different vinyl monomers. The type and content of the functional groups was modulated on the basis of feed composition and the nature of the functional comonomer selected among 2-hydroxyethyl methacrylate, diethyleneglycol methacrylate, methacrylic acid, vinyl acetate, N-vinyl-2-pyrrolidinone, N-isopropylacrylamide, and 2-(N,N-dimethylamino)ethyl methacrylate. The solubility, molecular weight, and acid-base properties exhibited polyelectrolyte behavior for all copolymers in solution.

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Section: Monomer Synthesismentioning

confidence: 99%

“…Finally, 6-methacryloyloxyhexanoic acid was obtained by the hydrolysis of t-butyl 6-methacryloyloxyhexanoate in acetonitrile in the presence of p-toluenesulfonic acid as acid catalyst [25]. The overall yield was only 2.5%, however, there is ample room for improvement by optimizing the synthetic steps.…”

Section: Monomer Synthesismentioning

confidence: 99%