On the synthesis of xenon(VI) fluorobismuthate(V)

Single-crystal structure determination of NO2SbF6, XeF5SbF6 and XeF5Sb2F11

“…The XeF 5 SbF 6 single-crystal determination revealed that the compound is isotypic to the known XeF 5 MF 6 (M = Ru [6], Pt [9]) as previously suggested on the basis of the X-ray powder diffraction data [11]. Both, the cation and the anion are located at mirror planes.…”

“…In the second are the Nb, Ru, Pt, Sb and according to X-ray powder diffraction data also the Ta [5,39], Ir [7,8] and Os [8] compounds. The uranium compound is the only example of the third group; meanwhile no structural information is available for the V [3] or the Bi compound [11].…”

“…XeF 5 SbF 6 was also investigated by 19 F NMR spectroscopy in an anhydrous hydrogen solution [2]. According to the available literature there are twelve known compounds of the type XeF 5 MF 6 (M = V [3], Nb [4], Ta [5], Ru [6], Ir [7], Os [8], Pt [9], Au [8], As [10], Sb [1], Bi [11] and U [12]). In some reviews [XeF 5 ] + [PdF 6 ] À with Pd(V) is mentioned [13][14][15].…”