“…Another argument for the necessity of 3D simulations when studying the interaction of GWs and photochemical processes derives from the fact that the MLT can be considered as a nonlinear chemical oscillator enforced by the diurnal cycle of solar insolation [ Sonnemann and Fichtelmann , 1987; Fichtelmann and Sonnemann , 1987, 1992]. This system is able to produce chemical resonances, subharmonic oscillations, and chaotic attractors [ Sonnemann and Fichtelmann , 1997; Sonnemann , 2001; Sonnemann and Grygalashvyly , 2003, 2005], all of which requires 3D dynamics for a theoretical description. The influence of turbulent diffusion on the nonlinear behavior of the photochemical system was investigated by means of sensitivity studies, showing a complicated model response when using the diffusion coefficient as a control parameter [ Sonnemann and Feigin , 1999a, 1999b; Sonnemann et al , 1999].…”