The results obtained by the analysis of raw materials and product samples collected from the three industries in Abu Zaabal area for the elements U, Th, La, Ce, Gd, Cr, Sb, Sc, Hf, Na, Fe, Lu, Zn and Au in the samples under study are presented and discussed.U content (in ppm) was found to be as follows: phosphate ore = 72.6, GSSP = 50.45, SSP = 42.65, DCP = 8.36, Gypsum = 5.31 and GNPK = 4.664. The La content in the phosphate ore is 40.0 ppm. The Cr content in fertilizers is in the range 12.12 -19.56 ppm except gypsum that has the lowest value of 0.406 ppm.In the alum company as well as ARACEMCO samples all the important elements have been analyzed either in the raw materials or in the products using NAA, namely U, Th, lanthanides as well as other elements.U, Ce, Co La, Cr .... etc. contents in the reference water samples are compared with two drainage water samples. Also U, Ce, Cr and Th have been analyzed.All the elements content in the leaf samples collected from AZFC zone are higher than their values in the reference leaf samples from Mounofia. Also, the elements content of the unwashed sample is higher than the values found in the same but washed sample.The measurements of the natural radioactivity in phosphate ore and in some fertilizer samples from AZFC are compared with the corresponding values obtained by NAA technique for the same samples. The comparison shows a negligible difference as regards the uranium content for each sample.