On trapped noble gases in ureilites

Abstract

Bulk samples of Goalpara, Haverö, Novo Urei, and carbon‐rich veins from all seven ureilites have been analyzed for He, Ne, Ar, Kr, and Xe by mass spectrometry by employing the stepwise heating technique. In all cases, trapped rare gases of the fractionated ‘planetary’ type are found to be strongly enriched in the vein material, up to at least 600‐fold over the silicates. Gas contents of the vein material from different ureilites vary considerably; the range in concentrations increases from a factor of 7 for He and Ne to a factor of 70 for Xe. Consequently, the elemental abundance ratios vary as well: 23 ≤ 4He/132Xe ≤ 500; 0.35 ≤ 20Ne/132Xe ≤ 10; 119 ≤ 36Ar/132Xe ≤ 1090, and 0.91 ≤ 84Kr/132Xe ≤ 3.05. The isotopic compositions, on the other hand, are indistinguishable from one another in all cases except for 40Ar/36Ar. Some characteristic ratios are 20Ne/22Ne = 10.70 ± 0.25 (for 0.03 ≤ 21Ne/22Ne ≤ 0.05), 36Ar/38Ar = 5.26 ± 0.06, and 129Xe/132Xe / 1.035 ± 0.005. The lowest measured 40Ar/36Ar ratio is (1.17 ± 0.20) × 10−3, which, after correction for the extraction blank, yields a new upper limit for the primordial 40Ar/36Ar ratio of (2.9 ± 1.7) × 10−4. Of the main constituents of carbon‐rich veins graphite, diamonds, and kamacite— graphite is shown to be void of trapped gases, while samples which show only the X ray diffraction lines of diamond have very high gas contents. In addition, there must be present at least one more carrier containing noble gases with a nuclide abundance pattern distinctly different from that observed for the diamonds and with gas contents even higher than in the diamonds. Its identity is not known at present. Physical adsorption and ambipolar diffusion are discussed as potential mechanisms responsible for the fractionation pattern observed. For adsorption to make the observed abundances compatible with the predicted ones, heavy neon losses (≈99%) must have occurred. If they were accompanied by an isotopic fractionation, it is possible that the neon initially was of solar composition. Ambipolar diffusion predicts the abundance ratios observed for (T ≈ 8500 K) provided that a means can be found to incorporate the ions into the carrier without any significant additional fractionation. In this case the isotope ratios observed would correspond to the ones in the partially ionized medium where the incorporation occurred.

Heavy noble gases in solar wind delivered by Genesis mission

“…2 Göbel et al, 1978), suggesting that all of the 40 Ar is from terrestrial contamination and we assume that it is not significantly isotopically fractionated. There is no simple way to verify this assumption but Ar blanks are always of atmospheric composition and, since the 40 Ar is small anyway, this assumption is not very important for the corrections.…”

Vapor-growth carbon and the origin of carbonaceous material in ureilites.

“…4, the noble gases in the 2000°C fraction of the MWCVD diamond sample are also plotted for comparison. We calculated the relative ion abundance in the plasma using the equation (sim plified from Gobel et al, 1978):…”

Osmium isotope systematics of ureilites

“…These isotopic heterogeneities are thought to preserve the primordial nebular heterogeneity in the accreting ureilite precursor materials and thus argue against a global magmatic equilibration of the ureilite parent body. Another apparently nebular signature that seems to preclude the significant outgassing that is expected from extensive magmatic processing is the high abundance of fractionated primordial noble gases that reside mostly in diamond (Begemann and Ott, 1983;Göbel et al, 1977;Rai et al, 2003b).…”