In this work, we bring to light the properties of newly formed polynomial sequences at each vertex of Pell polynomial sequences placed clockwise at each vertex in the n-gon. We compute the relation among the polynomials with such vertices. Moreover, in an n-gon, we generate a recurrence relation for a sequence giving the mth term formed at the kth. Similar to the situations we are talking about, we applied to Pell-Lucas polynomials, Jacobsthal polynomials, and Jacobsthal-Lucas polynomials and have obtained new relations recurrence.