In scattering experiments, physicists observe so-called resonances as peaks at certain energy values in the measured scattering cross sections per solid angle. These peaks are usually associate with certain scattering processes, e.g., emission, absorption, or excitation of certain particles and systems. On the other hand, mathematicians define resonances as poles of an analytic continuation of the resolvent operator through complex dilations. A major challenge is to relate these scattering and resonance theoretical notions, e.g., to prove that the poles of the resolvent operator induce the above mentioned peaks in the scattering matrix. In the case of quantum mechanics, this problem was addressed in numerous works that culminated in Simon's seminal paper [33] in which a general solution was presented for a large class of pair potentials. However, in quantum field theory the analogous problem has been open for several decades despite the fact that scattering and resonance theories have been well-developed for many models. In certain regimes these models describe very fundamental phenomena, such as emission and absorption of photons by atoms, from which quantum mechanics originated. In this work we present a first non-perturbative formula that relates the scattering matrix to the resolvent operator in the massless Spin-Boson model. This result can be seen as a major progress compared to our previous works [13] and [12] in which we only managed to derive a perturbative formula. processes, and thus, prove an analogous result that was obtained by Simon in [33] for the N-body Schrödinger operator in this particular model of quantum field theory. More precisely, we show that the pole of a meromorphic continuation of the integral kernel of the scattering matrix is located precisely at the resonance energy. The objective in this result is to contribute to the understanding of the relation between resonance and scattering theory. In our previous works [13] and [12], we were already able to derive perturbative results of this kind in case of the massless and massive Spin-Boson models, respectively. However, both results are only given in leading order with respect to the coupling constant. The present work can be seen as a major improvement of these pertubative results because it provides a closed and non-perturbative formula that connects the integral kernel of the scattering matrix elements for one-boson processes in terms of the dilated resolvent.Our results are based on the well-established fields of scattering and resonance theories and the numerous works in the classical literature of which we want to give a short overview here. Resonance theory, in the realm of quantum field theory, has been developed in a variety of models; see, e.g., [6,8,7,4,9,1,26,27,32,21,15,28,29,2,3,14]. In these works, several techniques have been invented for massless models of quantum field theory in order to cope with the absence of a spectral gap. Scattering theory has also been developed in various models of quantum field theory (see, e....