One-dimensional carbon chains encapsulated in hollandite
Jonathan M. Polfus
Abstract:One-dimensional carbon chains are highly reactive allotropes that are stabilized inside the protective environment of carbon nanotubes. Here we show that carbon chains can be encapsulated in metal oxides containing open structural channels, exemplified by hollandite α-MnO2. The α-MnO2 channels stabilize cumulene chains due to their structural commensurability, whereas the triple bonds in polyyne chains exhibit excessive steric repulsion to the oxide ions bordering the channel. Cumulene exhibits an interaction … Show more
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