2016
DOI: 10.1007/s12274-016-1033-x
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One-dimensional Cu-based catalysts with layered Cu–Cu2O–CuO walls for the Rochow reaction

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Cited by 51 publications
(14 citation statements)
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“…Among them, M2 is the most desired as it is the most important monomer used for the synthesis of the organosilicon polymers. Although many Cu-based catalysts have been reported to date [ 35–37 ], there is still room to improve the M2 selectivity and yield. It is expected that Zn 1 -Sn 1 /CuO with its unique structure might exhibit an outstanding catalytic property.…”
Section: Resultsmentioning
confidence: 99%
“…Among them, M2 is the most desired as it is the most important monomer used for the synthesis of the organosilicon polymers. Although many Cu-based catalysts have been reported to date [ 35–37 ], there is still room to improve the M2 selectivity and yield. It is expected that Zn 1 -Sn 1 /CuO with its unique structure might exhibit an outstanding catalytic property.…”
Section: Resultsmentioning
confidence: 99%
“…photo voltaic) [27,28]. One cannot discount applications in catalysis as well, since surface of certain oxides of copper can be metallic [29,30]. Prior to this work, copper oxide QDs of radius ~4-5 nm have been reported by Yee-Fun Lim et al , s work based on solution approach [28].…”
Section: Introductionmentioning
confidence: 99%
“…80 years after the independent discovery by R. Müller and E. G. Rochow, the direct synthesis reaction, given in eqn (1), remains the most common method for the synthesis of organosilicon compounds. [1][2][3][4][5][6][7] Si(s) + 2CH 3 Cl(s) → (CH 3 ) 2 SiCl 2 (g) (1) It is an important industrial process with a high amount of silicones produced per year (2.4 million metric tons in 2019) 8 with major applications such as construction, electronics, transportation, medical, personal care and others. 5 Therefore, the optimization of the silicones production via the increase in production yield is crucial as well as better energy efficiency and raw materials utilization and lower greenhouse gas emissions.…”
Section: Introductionmentioning
confidence: 99%