One-dimensional heterometallic Bi/Ag and Sb/Ag bromometalates(iii): structures, thermal stability and optical properties

Abstract

Silver-containing heterometallic bromobismuthates(III) (3-BrPyC3){[BiAgBr6]} (1) and (ImC4){[BiAgBr6]} (2) and bromoantimonate (ImC4)3{[Sb3Ag2Br17]} (3) (3-BrPyC3 – 1,6-bis(3-bromopyridin-1-ium)propane dication, ImC4 – diprotonated 1,4-bis(1H-imidazol-1-yl)butane) were synthesized. All compounds are comprised of infinite chains, featuring...