One‐Dimensional Nanostructured Metal Oxides for Lithium Ion Batteries

Li, Huiqiao; Li, De; Zhou, Haoshen

doi:10.1002/9781118310342.ch13

Cited by 4 publications

(2 citation statements)

References 108 publications

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“…Since CNTs were first discovered by Iijima [ 123 ], 1D nanomaterials with similar structures have been widely studied. The structural features of 1D nanomaterials not only include nanoscale and microscale joint effects, but also contain high aspect ratio and oriented growth direction [ 124 ]. Therefore, 1D nanomaterials are beneficial for fast transportation of electrons and ions and have an impact on tolerating the stress changes, which was considered as a class of most promising materials for high performances of energy storage systems [ 125 ].…”

Section: One-dimensional Nanomaterials For Pibsmentioning

confidence: 99%

Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions

et al. 2020

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Potassium ion batteries (PIBs) with the prominent advantages of sufficient reserves and economical cost are attractive candidates of new rechargeable batteries for large-grid electrochemical energy storage systems (EESs). However, there are still some obstacles like large size of K+ to commercial PIBs applications. Therefore, rational structural design based on appropriate materials is essential to obtain practical PIBs anode with K+ accommodated and fast diffused. Nanostructural design has been considered as one of the effective strategies to solve these issues owing to unique physicochemical properties. Accordingly, quite a few recent anode materials with different dimensions in PIBs have been reported, mainly involving in carbon materials, metal-based chalcogenides (MCs), metal-based oxides (MOs), and alloying materials. Among these anodes, nanostructural carbon materials with shorter ionic transfer path are beneficial for decreasing the resistances of transportation. Besides, MCs, MOs, and alloying materials with nanostructures can effectively alleviate their stress changes. Herein, these materials are classified into 0D, 1D, 2D, and 3D. Particularly, the relationship between different dimensional structures and the corresponding electrochemical performances has been outlined. Meanwhile, some strategies are proposed to deal with the current disadvantages. Hope that the readers are enlightened from this review to carry out further experiments better.

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Section: One-dimensional Nanomaterials For Pibsmentioning

confidence: 99%

Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions

et al. 2020

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“…Normally, b = 0.5 indicates a standard diffusioncontrolled behavior and b = 1.0 represents the surfacecontrolled capacitive behavior. 62 The peak current (i) is not proportional to the square root of the scan rate (v) with scan rate increasing, suggesting that the redox reaction process involves hybrid storage behaviors. 63,64 As shown in Figure 4b, the b-values of MA-Ti 3 C 2 are fitted as 0.92 and 0.88, declaring that the Li + -storage mechanism is mainly controlled by surfacecontrolled capacitive behavior.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

Diacid Molecules Welding Achieved Self-Adaption Layered Structure Ti₃C₂MXene toward Fast and Stable Lithium-Ion Storage

Liu

Zhang

et al. 2021

ACS Sustainable Chem. Eng.

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Ti 3 C 2 has been considered as a potential material for lithium-ion storage because of its abundant surface terminals, excellent metal-like conductivity, and modifiable layered structure. However, the Li + diffusion rate in interlayer is limited by the small interlayer spacing determined by the van der Waals forces. Herein, the dehydration condensation reaction between amino-functionalized Ti 3 C 2 (Ti 3 C 2 -NH 2 ) and maleic acid (MA) molecules was utilized to enlarge the interlayer spacing of Ti 3 C 2 . The MA molecules were successfully welded into interlayers of Ti 3 C 2 by HN−CO bonds (namely, chemical welding) and MA chemical welded Ti 3 C 2 (MA-Ti 3 C 2 ) with self-adaption layered structure were obtained. The MA molecules can contribute double effects to the layered structure of Ti 3 C 2 , and they act as chains to remit the volume change during Li + insertion and serve as pillars to enhance the structure stability during Li + extraction. The MA-Ti 3 C 2 exhibits an interlayer spacing of 1.28 nm, a fast Li + diffusion rate (1.4 × 10 −8 to 5.8 × 10 −7 cm 2 s −1 ), and improved Li + storage performance. The MA-Ti 3 C 2 //AC lithium-ion capacitor (LIC) demonstrates an excellent energy density of 102.5 Wh kg −1 at 200 W kg −1 and cycle stability with 76.3% at 1.0 A g −1 after 1000 cycles. This novel chemical welding delivers an effective perspective for modifying the layered structure, enhancing the structure stability, and achieving fast Li + diffusion and high-rate capability of twodimension materials.

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Flexible carbon nanostructures with electrospun nickel oxide as a lithium-ion battery anode

Lalia¹,

Khalil²,

Shah³

et al. 2015

Ionics

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Carbon nanostructures (CNS) with high electrical conductivity and unique branched structure of carbon nanotubes combined with NiO nanofibers (NFs) were used as anode for lithium-ion batteries. CNS works as a framework substrate for the anodic conversion reaction of nickel oxide (NiO). Electrochemical performance and behavior of CNS/ NiO anodes is compared with the conventional carbon (C)/ NiO anodes. CNS/NiO NF-based anode retains high specific capacity under different current densities compared to C/NiO anode. Moreover, specific capacity as high as 450 mAh/g for CNS/NiO NF anode is observed compared to only 90 mAh/g for C/NiO NFs using a current density of 500 mA/g after 500 cycles. This improved performance is attributed to the highly conductive network of CNS leading to efficient charge transfer. The high porosity, electrical conductivity as well as the branched and networked nature of CNS reveal to be of critical importance to allow the electrochemical conversion reactions.

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One‐Dimensional Nanostructured Metal Oxides for Lithium Ion Batteries

Cited by 4 publications

References 108 publications

Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions

Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions

Diacid Molecules Welding Achieved Self-Adaption Layered Structure Ti₃C₂MXene toward Fast and Stable Lithium-Ion Storage

Flexible carbon nanostructures with electrospun nickel oxide as a lithium-ion battery anode

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One‐Dimensional Nanostructured Metal Oxides for Lithium Ion Batteries

Cited by 4 publications

References 108 publications

Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions

Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions

Diacid Molecules Welding Achieved Self-Adaption Layered Structure Ti3C2MXene toward Fast and Stable Lithium-Ion Storage

Flexible carbon nanostructures with electrospun nickel oxide as a lithium-ion battery anode

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Diacid Molecules Welding Achieved Self-Adaption Layered Structure Ti₃C₂MXene toward Fast and Stable Lithium-Ion Storage