One-dimensional tunnel VO<sub>2</sub>(B) cathode materials for high-performance aqueous zinc ion batteries: a mini review of recent advances and future perspectives

Kou, Lingjiang; Wang, Yong; Song, Jiajia; Ai, Taotao; Li, Wenhu; Wattanapaphawong, Panya; Kajiyoshi, Koji

doi:10.1039/d3gc03887d

Green Chem.

2024

DOI: 10.1039/d3gc03887d

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One-dimensional tunnel VO₂(B) cathode materials for high-performance aqueous zinc ion batteries: a mini review of recent advances and future perspectives

Lingjiang Kou,

Yong Wang,

Jiajia Song

et al.

Abstract: Aqueous zinc ion batteries (AZIBs) are garnering significant attention as a promising energy storage system owing to their high safety, low cost, and environmental friendliness. Among various cathode materials, one-dimensional...

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Cited by 7 publications

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Efficient and Effective Synthesis of CaV₆O₁₆·2.7H₂O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Li,

Liu,

et al. 2024

Advanced Energy Materials

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Vanadium oxide‐based materials are considered to be among the most promising positive electrode candidates for aqueous zinc‐metal batteries (AZMBs). However, complex processes, high costs, and insufficient yields of their preparation methods limit further application. Herein, an efficient and effective oil bath method is presented for the preparation of CaV6O16·2.7H2O (CaVO), offering promising performance as cathode material for AZMBs. With commercial crystalline V2O5, Ca(CH3COO)2, and water as raw materials, phase‐pure CaVO with 42.8 g per batch and a yield of 98.8% can be obtained through the reaction at 90 °C for 6 h. It is further demonstrated that the pre‐intercalated Ca2+ and H2O not only expand the interlayer spacing from 4.38 Å for V2O5 to 8.21 Å for CaVO but also stabilize the interlayer structure of vanadium oxides, promoting the reversibility of CaVO toward the de‐/intercalation of Zn2+/H+. In addition, density‐functional theory calculations show that the introduction of Ca2+ and H2O effectively improves the diffusion kinetics of Zn2+ in CaVO. As a result, CaVO provides high specific capacity (379 mAh g−1 at 0.05 A g−1) and promising long‐term cyclability (94.4% capacity retention after 2200 cycles at 1 A g−1), demonstrating the efficient and effective synthesis of vanadium oxide‐based cathode materials for high‐performance AZMBs.

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Efficient and Effective Synthesis of CaV₆O₁₆·2.7H₂O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Li,

Liu,

et al. 2024

Advanced Energy Materials

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Mn2+-doped (NH4)2V4O9 cathode materials for highly stable aqueous zinc-ion batteries

Yuan,

Zhao,

Liu

et al. 2024

J Solid State Electrochem

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Dual-Salt aqueous electrolyte for enhancing Charge-Storage properties of VO2 polymorphic cathodes for Zn-Ion batteries

Huang,

Luo,

Kuo

et al. 2024

Chemical Engineering Journal

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One-dimensional tunnel VO₂(B) cathode materials for high-performance aqueous zinc ion batteries: a mini review of recent advances and future perspectives

Abstract: Aqueous zinc ion batteries (AZIBs) are garnering significant attention as a promising energy storage system owing to their high safety, low cost, and environmental friendliness. Among various cathode materials, one-dimensional...

Cited by 7 publications

References 65 publications

Efficient and Effective Synthesis of CaV₆O₁₆·2.7H₂O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Efficient and Effective Synthesis of CaV₆O₁₆·2.7H₂O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Mn2+-doped (NH4)2V4O9 cathode materials for highly stable aqueous zinc-ion batteries

Dual-Salt aqueous electrolyte for enhancing Charge-Storage properties of VO2 polymorphic cathodes for Zn-Ion batteries

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One-dimensional tunnel VO2(B) cathode materials for high-performance aqueous zinc ion batteries: a mini review of recent advances and future perspectives

Abstract: Aqueous zinc ion batteries (AZIBs) are garnering significant attention as a promising energy storage system owing to their high safety, low cost, and environmental friendliness. Among various cathode materials, one-dimensional...

Cited by 7 publications

References 65 publications

Efficient and Effective Synthesis of CaV6O16·2.7H2O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Efficient and Effective Synthesis of CaV6O16·2.7H2O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Mn2+-doped (NH4)2V4O9 cathode materials for highly stable aqueous zinc-ion batteries

Dual-Salt aqueous electrolyte for enhancing Charge-Storage properties of VO2 polymorphic cathodes for Zn-Ion batteries

Contact Info

Product

Resources

About

One-dimensional tunnel VO₂(B) cathode materials for high-performance aqueous zinc ion batteries: a mini review of recent advances and future perspectives

Efficient and Effective Synthesis of CaV₆O₁₆·2.7H₂O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries

Efficient and Effective Synthesis of CaV₆O₁₆·2.7H₂O as High‐Performance Cathode Material for Aqueous Zinc Metal Batteries