A large
amount of wool produced in the EU region is coarse and of low quality.
The limited or nonutilization of such coarse wool leads to landfilling
causing environmental pollution. In this paper, we studied the properties
of keratin hydrolyzate, produced by a sustainable hydrolysis process,
to be used as a foaming agent in foam dyeing of cotton and wool fabrics.
This is a preliminary step on the way to find possible applications
which overcome the environmental problem of wool waste and byproducts.
We report for the first time the use of keratin hydrolyzate as a foaming
auxiliary in the textile dyeing process. The surface tension, molecular
weight, foam stability, blow ratio, and bubble size of keratin hydrolyzate
in aqueous solutions with and without dyeing auxiliaries were determined.
The dyeing influential parameter such as wet pickup was studied to
identify their effect on dye fixation and color strength. The foam
dyeing was compared with conventional cold-pad batch and pad-steam
processes for cotton and wool, respectively. In the investigated variant,
keratin hydrolyzate shows a reduction in surface tension, good foam
stability along with dyeing auxiliaries, a blow ratio of about 10:1,
and 0.02–0.1 mm diameter bubble sizes. These results make possible
its application as a foaming agent. Cotton and wool fabrics were dyed
using reactive and acid dyes respectively, on a horizontal padding
mangle. In both cases, hydrolyzed keratin acts as a carrier for dye
molecules and the mechanism of dyeing depends on the respective pH
of the dye solution, keratin, and fiber. Foam dyeing of cotton resulted
in comparable color strength, while wool shows higher color strength
when compared with conventional dyeing processes. Washing and rubbing
fastness of cotton and wool foam dyed fabrics are similar to the respective
conventional dyed fabrics. The combinations of sustainable keratin
hydrolyzate production and its use as an eco-friendly, biodegradable
foaming agent in less add on foam dyeing technology resulted not only
in saving of large amounts of water and energy but also will be helpful
in minimizing a load on effluent and the environment.