One-pot synthesis of 2,5-diformylfuran from fructose using a magnetic bi-functional catalyst

Mittal, Neha; Nisola, Grace M.; Malihan, Lenny B.; Seo, Jeong Gil; Kim, Hern; Lee, Seong Poong; Chung, Wook–Jin

doi:10.1039/c6ra01549b

Cited by 44 publications

(24 citation statements)

References 61 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It is used in the synthesis of fungicides, drugs, and polymeric materials [85]. Several promising catalytic routes for 2,5-DFF production are reported in the literature [85][86][87][88][89][90][91]. The complete transformation of 5-HMF with a 90% yield of 2,5-DFF was achieved with V 2 O 5 /TiO 2 catalyst in the presence of air and toluene or methyl isobutyl ketone (MIBK) as the solvent.…”

Section: -Hmf Derivativesmentioning

confidence: 99%

“…Researchers also disclosed the potential of iron as a cheap catalyst for the production of 2,5-DFF from 5-HMF [87,88]. Mittal et al [89] reported the use of magnetic bi-functional WO 3 HO-VO (salen)-SiO 2 @Fe 2 O 3 nano-catalyst to directly synthesize 2,5-DFF from fructose. In this work, an 82% yield of 5-HMF was obtained in 1 h and if a co-oxidant (H 2 O 2 ) was added, 71% 2,5-DMF was synthesized after 15 h in the presence of ambient air.…”

Section: -Hmf Derivativesmentioning

confidence: 99%

See 1 more Smart Citation

Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

2019

View full text Add to dashboard Cite

The production of chemicals from biomass, a renewable feedstock, is highly desirable in replacing petrochemicals to make biorefineries more economical. The best approach to compete with fossil-based refineries is the upgradation of biomass in integrated biorefineries. The integrated biorefineries employed various biomass feedstocks and conversion technologies to produce biofuels and bio-based chemicals. Bio-based chemicals can help to replace a large fraction of industrial chemicals and materials from fossil resources. Biomass-derived chemicals, such as 5-hydroxymethylfurfural (5-HMF), levulinic acid, furfurals, sugar alcohols, lactic acid, succinic acid, and phenols, are considered platform chemicals. These platform chemicals can be further used for the production of a variety of important chemicals on an industrial scale. However, current industrial production relies on relatively old and inefficient strategies and low production yields, which have decreased their competitiveness with fossil-based alternatives. The aim of the presented review is to provide a survey of past and current strategies used to achieve a sustainable conversion of biomass to platform chemicals. This review provides an overview of the chemicals obtained, based on the major components of lignocellulosic biomass, sugars, and lignin. First, important platform chemicals derived from the catalytic conversion of biomass were outlined. Later, the targeted chemicals that can be potentially manufactured from the starting or platform materials were discussed in detail. Despite significant advances, however, low yields, complex multistep synthesis processes, difficulties in purification, high costs, and the deactivation of catalysts are still hurdles for large-scale competitive biorefineries. These challenges could be overcome by single-step catalytic conversions using highly efficient and selective catalysts and exploring purification and separation technologies.

show abstract

Section: -Hmf Derivativesmentioning

confidence: 99%

Section: -Hmf Derivativesmentioning

confidence: 99%

Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

2019

View full text Add to dashboard Cite

show abstract

“…Graphene oxide used as a highly active catalyst for one‐pot conversion of fructose to DFF . A magnetic nanocatalyst bi‐functional WO 3 HO‐VO (Salten)‐SiO 2 @Fe 3 O 4 was used to directly synthesize DFF from fructose with the addition of H 2 O 2 as co‐oxidant . A highly active V‐containing all‐silica beta (VSi‐Beta) zeolite for the one‐pot and one‐step conversion of various carbohydrates into DFF with sulfuric acid as co‐catalyst and atmospheric oxygen .…”

Section: Introductionmentioning

confidence: 99%

Co‐Al Hydrotalcites: Highly Active Catalysts for the One‐Pot Conversion of Fructose to 2,5‐Diformylfuran

Raut

Bhanage

2018

ChemistrySelect

View full text Add to dashboard Cite

In this work, a series of Co−Al hydrotalcites were synthesized in the molar ratio of 1:1(cat‐3), 2:1(cat‐4), 3:1(cat‐5). These synthesized Co−Al hydrotalcites were characterized by different characterization techniques such as XRD, XPS, FT‐IR, SEM, EDX, TGA, and N2 physical adsorption. The catalytic properties of the prepared Co−Al hydrotalcites in different molar ratio were investigated for the dehydration of fructose to 5‐hydroxymethylfurfural (HMF), and selective oxidation of the HMF into 2,5‐diformylfuran (DFF). The complete conversion of HMF led to 95% yield of DFF at 120 °C under 3 bar oxygen pressure in dimethyl sulfoxide (DMSO) for 6 h. DFF in the yield of 87% with 100% conversion of fructose could be achieved in a one pot and two‐step reaction using Co−Al calacite in ratio of 2:1(cat‐4). A 77% yield of DFF was obtained in one‐pot and one‐step reaction using the same hydrotalcite catalyst. A DFF yield of 59% was achieved in a one pot and one‐step reaction using air as oxidant. After completion of the reaction, the catalyst can be separate very easily and can be reused up to four times without any significant loss in its catalytic activity.

show abstract

“…The conversion of carbohydrates to platform compounds such as 5-(hydroxymethyl) furfural (HMF), [6][7][8][9][10] furfural, [11][12][13] levulic acid (LA) 14,15 and the utilization of platform compounds have both been extensively researched. Furfuryl alcohol, [16][17][18][19][20] tetrahydrofurfuryl alcohol, 21,22 dimethylfuran, 23 2,5-furandicarboxylic acid, 24 diformylfuran, [25][26][27][28][29][30][31] cyclopentanone, 32,33 g-valerolactone, 14,[34][35][36] and tetrahydro-2,5-furandimethanol 37,38 are the typical target products.…”

Section: Introductionmentioning

confidence: 99%

Direct conversion of carbohydrates to diol by the combination of niobic acid and a hydrophobic ruthenium catalyst

Duan

Zhang

et al. 2017

RSC Adv.

View full text Add to dashboard Cite

show abstract

One-pot synthesis of 2,5-diformylfuran from fructose using a magnetic bi-functional catalyst

Abstract: A magnetic bi-functional WO3HO-VO(salten)-SiO2@Fe3O4nanocatalyst was prepared to directly synthesize 2,5-diformylfuran (2,5-DFF) from fructose.

Cited by 44 publications

References 61 publications

Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

Co‐Al Hydrotalcites: Highly Active Catalysts for the One‐Pot Conversion of Fructose to 2,5‐Diformylfuran

Direct conversion of carbohydrates to diol by the combination of niobic acid and a hydrophobic ruthenium catalyst

Contact Info

Product

Resources

About