One‐pot synthesis of 2H‐thiochromenes via TiCl4‐promoted reaction of 2‐tert‐butylthiobenzaldehydes with activated alkenes

Lee, Chang Hoon; Lee, Kee‐Jung

doi:10.1002/jhet.182

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Cited by 5 publications

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Copper‐Catalyzed Domino S_N2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

et al. 2013

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A variety of substituted quinoline/pyridine, thiochromene and naphthalene derivatives, which might be of biological and medicinal value, were synthesized by copper-catalyzed domino S N 2'/coupling, S N 2'/deacylation/coupling and S N 2'/coupling/elimination reactions. The method provides a general and convenient approach to the synthesis of various sub-stituted cyclic compounds from the corresponding Baylis-Hillman (B-H) acetates and N-/S-/C-nucleophiles.

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Copper‐Catalyzed Domino S_N2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

et al. 2013

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ChemInform Abstract: One‐Pot Synthesis of 2H‐Thiochromenes via TiCl₄‐Promoted Reaction of 2‐tert‐Butylthiobenzaldehydes with Activated Alkenes.

Lee

2010

ChemInform

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A Multi‐Component Reaction in the Morita–Baylis–Hillman Route

Pal¹,

Bhunia²

2013

Eur J Org Chem

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A facile stereoselective synthesis of trisubstituted (Z)/(E)‐alkenes containing a functionalized thioether unit has been accomplished by using a new three‐component tetramolecular reaction (ABCB′‐type) following a Morita–Baylis–Hillman (MBH) route. Syntheses beginning with preformed MBH adducts yield similar results (ABC‐type reaction) and broaden the scope of application. Suitably substituted aromatic aldehydes result in the formation of 3‐substituted‐2H‐thiochromenes in high yield.

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One‐pot synthesis of 2H‐thiochromenes via TiCl₄‐promoted reaction of 2‐tert‐butylthiobenzaldehydes with activated alkenes

Abstract: magnified imageA facile synthesis of 2H‐thiochromenes through TiCl4‐promoted reaction of 2‐tert‐butylthiobenzaldehydes with activated alkenes is described. J. Heterocyclic Chem., (2009).

Cited by 5 publications

References 40 publications

Copper‐Catalyzed Domino S_N2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

Copper‐Catalyzed Domino S_N2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

ChemInform Abstract: One‐Pot Synthesis of 2H‐Thiochromenes via TiCl₄‐Promoted Reaction of 2‐tert‐Butylthiobenzaldehydes with Activated Alkenes.

A Multi‐Component Reaction in the Morita–Baylis–Hillman Route

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One‐pot synthesis of 2H‐thiochromenes via TiCl4‐promoted reaction of 2‐tert‐butylthiobenzaldehydes with activated alkenes

Abstract: magnified imageA facile synthesis of 2H‐thiochromenes through TiCl4‐promoted reaction of 2‐tert‐butylthiobenzaldehydes with activated alkenes is described. J. Heterocyclic Chem., (2009).

Cited by 5 publications

References 40 publications

Copper‐Catalyzed Domino SN2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

Copper‐Catalyzed Domino SN2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

ChemInform Abstract: One‐Pot Synthesis of 2H‐Thiochromenes via TiCl4‐Promoted Reaction of 2‐tert‐Butylthiobenzaldehydes with Activated Alkenes.

A Multi‐Component Reaction in the Morita­–Baylis–Hillman Route

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Product

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One‐pot synthesis of 2H‐thiochromenes via TiCl₄‐promoted reaction of 2‐tert‐butylthiobenzaldehydes with activated alkenes

Copper‐Catalyzed Domino S_N2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

Copper‐Catalyzed Domino S_N2′/Coupling Reaction: A Versatile and Facile Synthesis of Cyclic Compounds from Baylis–Hillman Acetates

ChemInform Abstract: One‐Pot Synthesis of 2H‐Thiochromenes via TiCl₄‐Promoted Reaction of 2‐tert‐Butylthiobenzaldehydes with Activated Alkenes.

A Multi‐Component Reaction in the Morita–Baylis–Hillman Route