2017
DOI: 10.1002/ejoc.201700891
|View full text |Cite
|
Sign up to set email alerts
|

One‐Pot Synthesis of Butadiyne‐Bridged Bipyrrole Derivatives and Bisporphyrin

Abstract: Butadiyne‐bridged bipyrroles were prepared from 2‐iodopyrroles and trimethylsilylacetylene through a facile one‐pot synthesis involving a modified Sonogashira coupling reaction and in situ aerobic oxidative coupling of the acetylenic pyrroles; the products were obtained in yields of 31–72 % depending on the substituents on the pyrrole. The acetylene‐bridged diacids obtained from the hydrolysis of the corresponding ester derivatives are highly stable, unlike most reported oligopyrrolic diacids. This protocol co… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2018
2018
2018
2018

Publication Types

Select...
1

Relationship

0
1

Authors

Journals

citations
Cited by 1 publication
references
References 85 publications
0
0
0
Order By: Relevance