“…If an excess of another alkene is present, then the o -quinol dimer does not form. Kasturi, McNelis, Solomon, and Habicher 93 have reported similar observations. 41 [4 + 2] Dimerization of an o -quinone methide affords o -quinol derivative.…”
Section: 1 Preparationmentioning
confidence: 59%
“…89 If an excess of another alkene is present, then the o-quinol dimer does not form. Kasturi, 90 McNelis, 91 Solomon, 92 42). 94 Surprisingly, if the diene 157 is replaced with a less nucleophilic diene, then the [4 + 2] reaction proceeds with the enone olefin rather than the carbonyl residue.…”
“…If an excess of another alkene is present, then the o -quinol dimer does not form. Kasturi, McNelis, Solomon, and Habicher 93 have reported similar observations. 41 [4 + 2] Dimerization of an o -quinone methide affords o -quinol derivative.…”
Section: 1 Preparationmentioning
confidence: 59%
“…89 If an excess of another alkene is present, then the o-quinol dimer does not form. Kasturi, 90 McNelis, 91 Solomon, 92 42). 94 Surprisingly, if the diene 157 is replaced with a less nucleophilic diene, then the [4 + 2] reaction proceeds with the enone olefin rather than the carbonyl residue.…”
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