One-pot synthesis of two new metal–organic networks: hydrogen bonded mononuclear Cu(II) complex and mixed-valence Cu(I,II) coordination polymer with encapsulated 14-membered unique water cluster

Semerci, Fatih; Yeşılel, Okan Zafer; Yüksel, Fatma; Şahın, Onur

doi:10.1016/j.inoche.2015.10.016

Cited by 10 publications

(4 citation statements)

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“…Water is importance to life and plays a vital role in many physical, chemical and biological processes. [1][2][3][4] Water molecules have two hydrogen atoms and two lone pairs electrons, which make it possible to form four hydrogen bonds in tetrahedron form, but it can also show 3-coordinate configurations. [3] Unlike covalent bonds, the H-bond geometry is much more flexible.…”

Section: Introductionmentioning

confidence: 99%

“…Water cluster is a group of water molecules connected by hydrogen bonds, which has attracted a lot of attention due to its importance in understanding a great number of chemical processes. [1,5,6] In theory and experiment, chemists have studied the exact structural information of various hydrogen-bonded water aggregates with different sizes under the same environment. [7][8][9][10] Up to now, many interesting discrete water clusters (H 2 O) n , [11][12][13][14] one-dimensional (1D) chains/tape, [15,16] twodimensional (2D) layers, [17,18] and three-dimensional (3D) water networks [19,20] have been structurally characterized.…”

Section: Introductionmentioning

confidence: 99%

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Synthesis, Crystal Structure and Luminescent Properties of a 3D Mg(II)−Sm(III) Heterometallic Coordination Polymer Containing 20‐member Water Clusters

Chen

Liu

Lin

et al. 2020

Zeitschrift anorg allge chemie

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A new Mg(II)À Sm(III) heterometallic coordination polymer (Cp) with the formula [Sm 2 (pydc) 6 Mg 3 (H 2 O) 6 ] • 11H 2 O (1) (H 2 pydc = pyridine-2,6-dicarbolylic acid) has been solvothermal synthesized by reacting pyridine-2,6-dicarbolylic acid, Sm(NO 3) 3 • 6H 2 O, MgCl 2 • 6H 2 O and imidazole at 393 K for 48 h. It was characterized by single-crystal X-ray diffraction, elemental analysis, IR and TGA. The results show that coordination polymer 1 exhibits a three-dimensional network structure and crystallizes in hexagonal crystal system, space group P6/mcc, with crystallographic data of a = 15.4203(6) Å, b = 15.4203(6) Å, c = 15.2563(6) Å, α = β = 90°, γ = 120°, V = 3141.7(3) Å 3 , and Z = 2. The twentymember water cluster structure and topological structure of compound 1 were analyzed, and its luminescent properties were studied. It presents the characteristic emission spectra of Sm(III) ions.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Synthesis, Crystal Structure and Luminescent Properties of a 3D Mg(II)−Sm(III) Heterometallic Coordination Polymer Containing 20‐member Water Clusters

Chen

Liu

Lin

et al. 2020

Zeitschrift anorg allge chemie

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“…10 Among these methods, solvothermal/hydrothermal synthesis is the most important and common tool to obtain new, highly robust, and extended coordination polymers in single crystal form. 11,12 5-Sulfoisophthalic acid (sipH 3 ) is one such interesting ligand and has two functional groups, -SO 3 H and -COOH. Partly or fully deprotonated sipH 2− and sip 3− are useful building blocks for constructing coordination polymers and act as a versatility ligand and coordinate to metal ions as bridging ligand.…”

Section: Introductionmentioning

confidence: 99%

Syntheses and photoluminescence properties of new Zn(II) and Cd(II) coordination polymers prepared from 5-sulfoisophthalate ligand

Semerci¹

2017

Turk J Chem

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New coordination polymers, formulated as {[Zn( µ -sipH)( µ -apim)] · 3H 2 O} n (1) andwere synthesized based on the 1-(3-aminopropyl)imidazole (apim) along with 5-sulfoisophthalate (sip) ligands. The complexes were synthesized under mild hydrothermal conditions. All the complexes were characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction studies. The X-ray crystallographic studies of 1 and 2 reveal Zn(II) and Cd(II) ions are µ -bridged by dianionic sipH and trianionic sip ligands in bis(monodentate) and bis(bidentate) coordination mode, respectively, to generate 1D polymer chains. In complex 1, the adjacent chains are linked by two apim ligands to form a 1D nanotubular structure. Complex 2 is the first example of a protonated apimH ligand. In the complexes the adjacent 1D chains extend into a 3D supramolecular network by hydrogen bonds.The thermal decomposition behavior and photoluminescent property of the complexes are also discussed herein.

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“…As noted above an octamer is incorporated into an infinite net and also in an isolated cluster as seen in the one-dimensional material [C38H26Cu3N6O8]•7(H2O) that was reported by Semerci and coworkers. 159 That water cluster is an elaborate 14-molecule unit that is isolated in a rectangular cavity of the framework (~16 x 13 Å). This 14-molecule unit is formed by a central water octamer and two trimers appended to opposite ends ( Figure 86).…”

Section: Copper Metal Organic Materialsmentioning

confidence: 99%

Development of metal organic materials for use in novel water treatment schemes

Payne¹

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admirable, formidable, and kind, both as scientist and as person. I have learned much more than how to be a great scientist from her and for that, I am grateful. I wish her lab, and her career, all the best. I will be watching from afar. Josh de Groot and Ashini Jayasinghe were exemplary role models and I have enjoyed mild success only because they were senior to me. Madeline Basile and I began our Ph.Ds. together, and I could not have been luckier to have her along the way. I know the two of us grew quite a bit as scientists, and even more as people. Amy Charles and Sara Scheib of RWG, exposure to their bright minds, and non-chemist minds at that, is one of the major reasons I am so eager and confident to make my next move. Professor Sarah Larsen was a wonderful role model and mentor, I know she was working in the background to help get me where I am, and I am grateful. Professor Quinn's ability to captivate the organic chemistry classroom is what drew me to pursue undergraduate research in his lab. Without that experience along with the mentorship of Alex Lodge and Joe Topczewski I wouldn't be writing this right now. Jen Teitle in the graduate college helped with writing and career advice that proved instrumental. The undergrads I had the pleasure of working with: Taylor, Samantha, Maggie, Jay, and Vinny, were always an important part of the team. I worked hard to make sure they felt that way, and that they knew I was thankful for their work. The IT folks in our department often go unsung, but I would like to acknowledge them as well: Brian, Peter, and Michael often came to help quickly and always had a resolution at hand. v The grad students junior to me in Tori's lab who have helped, taught, and learned from me, I want to say thanks to you as well. Shohel, Lindsey, Mikaela, and Dmytro, I am excited for your futures and look forward to hearing about your careers. Keep that dewar full you guys!

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One-pot synthesis of two new metal–organic networks: hydrogen bonded mononuclear Cu(II) complex and mixed-valence Cu(I,II) coordination polymer with encapsulated 14-membered unique water cluster

Cited by 10 publications

References 65 publications

Synthesis, Crystal Structure and Luminescent Properties of a 3D Mg(II)−Sm(III) Heterometallic Coordination Polymer Containing 20‐member Water Clusters

Synthesis, Crystal Structure and Luminescent Properties of a 3D Mg(II)−Sm(III) Heterometallic Coordination Polymer Containing 20‐member Water Clusters

Syntheses and photoluminescence properties of new Zn(II) and Cd(II) coordination polymers prepared from 5-sulfoisophthalate ligand

Development of metal organic materials for use in novel water treatment schemes

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