One-step enzymatic grafting of ferulic acid with cellulose to enhance matrices–fibres compatibility in bio-composites

Morin, Sophie; Bockstal, Lauris; Jacquet, Nicolas; Richel, Aurore

doi:10.1007/s10853-019-03832-x

Cited by 14 publications

(10 citation statements)

References 18 publications

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“…The comparative SC50 values of the enzymatically modified and non-modified films are shown in Table 2. Initially, both the non-modified CS and the non-modified CMC showed no reduction in DPPH radicals, probably due to inter-and intramolecular hydrogen bonding, as previously reported in the literature [15,19].…”

Section: Estimation Of the Grafting Efficiency (Folin)supporting

confidence: 76%

“…However, a new peak appeared at 1269 cm −1 in the spectrum of the enzymatically modified CMC, while this peak was undetectable in the spectrum of the non-modified CMC. Furthermore, the wide peak at around 1015 cm −1 considerably increased in the CMC modified spectrum, probably suggesting an ether bond linkage [ 19 , 41 ]. Furthermore, an increase in the intensity of the peak at 2900 cm −1 appeared in the spectrum of modified CMC and could probably be attributed to the C–H of methyl (–CH 3 ) and methylene (–CH 2 ) phenolic groups [ 12 ].…”

Section: Resultsmentioning

confidence: 99%

“…The enzymatic modification of chitosan with a wide variety of bioactive compounds, such as phenolics [ 15 , 16 ] or flavonoids [ 17 , 18 ], has been extensively studied. Apart from chitosan, the enzymatic modification of other polymers, such as cellulose [ 19 ] and hybrid hydrogels consisting of chitosan and gelatin [ 20 , 21 ], has also attracted scientific interest recently, especially for biomedical applications, ranging from wound healing to tissue engineering and drug delivery applications.…”

Section: Introductionmentioning

confidence: 99%

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Development of a Multi-Enzymatic Approach for the Modification of Biopolymers with Ferulic Acid

et al. 2022

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A series of polymers, including chitosan (CS), carboxymethylcellulose (CMC) and a chitosan–gelatin (CS–GEL) hybrid polymer, were functionalized with ferulic acid (FA) derived from the enzymatic treatment of arabinoxylan through the synergistic action of two enzymes, namely, xylanase and feruloyl esterase. Subsequently, the ferulic acid served as the substrate for laccase from Agaricus bisporus (AbL) in order to enzymatically functionalize the above-mentioned polymers. The successful grafting of the oxidized ferulic acid products onto the different polymers was confirmed through ultraviolet–visible (UV–Vis) spectroscopy, attenuated total reflectance (ATR) spectroscopy, scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) spectroscopy. Additionally, an enhancement of the antioxidant properties of the functionalized polymers was observed according to the DDPH and ABTS protocols. Finally, the modified polymers exhibited strong antimicrobial activity against bacterial populations of Escherichia coli BL21DE3 strain, suggesting their potential application in pharmaceutical, cosmeceutical and food industries.

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Section: Estimation Of the Grafting Efficiency (Folin)supporting

confidence: 76%

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Development of a Multi-Enzymatic Approach for the Modification of Biopolymers with Ferulic Acid

et al. 2022

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“…Despite it was not explicitly mentioned in the work, it is very likely that the described modification was achieved thanks to the action of mediators, such as phenols, which might have been present in the enzymatic preparation. Recently, laccase‐grafted cellulose fibrils (MCC) were extruded in polypropylene‐grafted maleic acid (PPgMA) for mechanical properties studies [103] . Laccase from T. versicolor and ferulic acid were used to graft cellulose fibers to improve the compatibility with the polymer resin.…”

Section: Laccase‐mediated Grafting On Cellulosementioning

confidence: 99%

Enzymatic Modification of Cellulose To Unlock Its Exploitation in Advanced Materials

2020

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Nowadays natural biopolymers have a wide variety of uses in various industrial applications, such as food, adhesives and composite materials. Among them, cellulose has attracted the interest of researchers due to its properties: high strength and flexibility, biocompatibility and nontoxicity. Despite that, in many cases its practical use is limited because of poor solubility and/or an unsuitable hydrophilic/hydrophobic balance. In this context, enzymatic modification appears as a powerful strategy to overcome these problems through selective, green and environmentally friendly processes. This minireview discusses the different methods developed for the enzymatic modification of cellulose, emphasizing the type of reaction, the enzymes used (laccases, esterases, lipases, hexokinases, etc.), and the properties and applications of the cellulose derivatives obtained. Considering that cellulose is the most abundant natural polymer on Earth and can be derived from residual lignocellulosic biomass, the impact of its use in bio‐based process following the logic of the circular economy is relevant.

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“…[ 7 ] Ferulic acid (FA) is a typical biomass derived primarily from lignin, and has been substantially studied for developing polymers, [ 8–10 ] especially polyesters. [ 11–13 ] More recently, a new type of core/shell polymeric latex particles was fabricated by Caillol et al. [ 14 ] using FA as raw material.…”

Section: Introductionmentioning

confidence: 99%

Biomass‐Derived Acetylenic Polymer Monoliths Prepared by High Internal Phase Emulsion Template Method and Used for Adsorbing Cationic Pollutants

Yang

Yong

Zhao

et al. 2021

Macro Chemistry & Physics

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A new type of biobased porous polymer monolith is prepared starting from biomass, ferulic acid (FA), via high internal phase emulsion (HIPE) template polymerization method. FA is transferred into an acetylenic monomer, which undergoes catalytic HIPE polymerization, eventually forming a porous monolith named as PolyHIPE. The phenolic hydroxyl groups in the monolith are functionalized with sodium hydroxide, forming PolyHIPE‐Na+ and meanwhile transforming the initial hydrophobic monolith into a hydrophilic one. The formation and structure of the monoliths are characterized with Fourier transform infrared (FT‐IR), NMR, and scanning electron microscope (SEM) techniques. The adsorption capacity of the monoliths is further investigated. PolyHIPE‐Na+ exhibits high adsorption capacity toward methylene blue (MB) and cetyltrimethylammonium bromide (CTAB) from simulated wastewater. The adsorption behavior of PolyHIPE‐Na+ is found to fit the pseudo second order kinetic model better. The adsorption isotherm can be well described by the Langmuir isotherm model. The maximum adsorption capacity for MB and CTAB are 1016 and 1390 mg g−1, respectively. The biobased FA derived monolithic adsorbent also shows desirable recycling usability and stability in adsorption−desorption cycles.

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One-step enzymatic grafting of ferulic acid with cellulose to enhance matrices–fibres compatibility in bio-composites

Cited by 14 publications

References 18 publications

Development of a Multi-Enzymatic Approach for the Modification of Biopolymers with Ferulic Acid

Development of a Multi-Enzymatic Approach for the Modification of Biopolymers with Ferulic Acid

Enzymatic Modification of Cellulose To Unlock Its Exploitation in Advanced Materials

Biomass‐Derived Acetylenic Polymer Monoliths Prepared by High Internal Phase Emulsion Template Method and Used for Adsorbing Cationic Pollutants

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