Online determination of 2 H/ 1 H and 13 C/ 12 C isotope ratios of cinnamaldehyde from different sources using gas chromatography isotope ratio mass spectrometry

Sewenig, Sabine; Hener, Uwe; Mosandl, Armin

doi:10.1007/s00217-003-0801-5

Cited by 23 publications

(27 citation statements)

References 9 publications

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“…Development of an isotope ratio authenticity range for the major compounds that are found in the essential oil is a reliable method to detect fraud (Sewenig and others ; Hrastar and others ; Greule and others ). For example, mandarin oil was shown to be adulterated by less expensive oils such as orange peel oil (Faulhaber and others ), and cassia cinnamon oil is often used in the adulteration of ceylon cinnamon oil (Sewenig and others ). A component typical of mandarin oil, methyl N ‐methylanthranilate (MNM), is not found in any other citrus peel oil and for this reason can be implemented in the detection of adulterants.…”

Section: Other Applications Of Gc‐c‐irms For the Study Of Aroma Compomentioning

confidence: 99%

Gas Chromatography‐Combustion‐Isotope Ratio Mass Spectrometry for Traceability and Authenticity in Foods and Beverages

Leeuwen

Prenzler

Ryan

et al. 2014

Comp Rev Food Sci Food Safe

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As consumers demand more certainty over where their food and beverages originate from and the genuineness of ingredients, there is a need for analytical techniques that are able to provide data on issues such as traceability, authenticity, and origin of foods and beverages. One such technique that shows enormous promise in this area is gas chromatographycombustion-isotope ratio mass spectrometry (GC-C-IRMS). As will be demonstrated in this review, GC-C-IRMS is able to be applied to a wide array of foods and beverages generating data on key food components such as aroma compounds, sugars, amino acids, and carbon dioxide (in carbonated beverages). Such data can be used to determine synthetic and natural ingredients; substitution of 1 ingredient for another (such as apple for pear); the use of synthetic or organic fertilizers; and origin of foods and food ingredients, including carbon dioxide. Therefore, GC-C-IRMS is one of the most powerful techniques available to detect fraudulent, illegal, or unsafe practices in the food and beverages industries and its increasing use will ensure that consumers may have confidence in buying authentic products of known origin.

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Section: Other Applications Of Gc‐c‐irms For the Study Of Aroma Compomentioning

confidence: 99%

Gas Chromatography‐Combustion‐Isotope Ratio Mass Spectrometry for Traceability and Authenticity in Foods and Beverages

Leeuwen

Prenzler

Ryan

et al. 2014

Comp Rev Food Sci Food Safe

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“…Since the first reports on on‐line techniques for bulk and compound‐specific 2 H and 18 O isotope analysis of organic compounds by means of pyrolytic or reductive sample conversion into H 2 and CO gas in the late 1990s,1–5 research using 2 H/ 18 O continuous‐flow isotope‐ratio mass spectrometry (CF‐IRMS) either in conjunction with other isotope analyses or on its own as a means to providing a new or additional source of information on authenticity, biochemical/environmental fate or provenance of a given compound or material has generated new insights and opened new doors in many areas of applied analytical chemistry including forensic sciences 6–18…”

mentioning

confidence: 99%

N₂: a potential pitfall for bulk ²H isotope analysis of explosives and other nitrogen‐rich compounds by continuous‐flow isotope‐ratio mass spectrometry

Meier‐Augenstein

Kemp²,

Lock

2009

Rapid Comm Mass Spectrometry

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Observations made during the (13)C isotope analysis of gaseous CO(2) in the simultaneous presence of argon in the ion source of the isotope ratio mass spectrometer prompted us to investigate what influence the simultaneous presence of nitrogen would have on both accuracy and precision of bulk (2)H isotope analysis of nitrogen-rich organic compounds. Initially an international reference material, IAEA-CH7, was mixed with silver nitrate in various ratios to assess the impact that N(2) evolved from the pyrolysis of nitrogen-rich organic compounds would have on measured delta(2)H-values of IAEA-CH7. In a subsequent experiment, benzoic acid was mixed with silver nitrate to mimic the N:H ratio of organic-rich nitrogen compounds such as cellulose nitrate and RDX. The results of both experiments showed a significant deterioration of both accuracy and precision for the expected delta(2)H values for IAEA-CH7 and benzoic acid when model mixtures were converted into hydrogen and nitrogen, and subsequently separated by gas chromatography using standard experimental conditions, namely a 60 cm packed column with molecular sieve 5 A as stationary phase held at a temperature of 85 degrees C. It was found that bulk (2)H stable isotope analysis of nitrogen-rich organic compounds employing published standard conditions can result in a loss of accuracy and precision yielding delta(2)H values that are 5 to 25 per thousand too negative, thus suggesting, for example, that tree-ring (2)H isotope data based on cellulose nitrate may have to be revised.

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“…Масло французской лаванды фальсифицируют разбавлением дешевым маслом болгарской лаванды или эфирными маслами других разновидностей рода Lavendula [69]. Эфирное масло кассии часто используют для фальсификации масла коричника цейлонского [70]. Более сложные по химическому составу и запаху масла апельсина, мандарина, лимона и грейпфрута, полученные холодным прессованием, могут быть разбавлены обедненными дистиллированными маслами этих же фруктов [71,72].…”

Section: способы фальсификации эфирных маселunclassified

“…Сочетание методов газовой хроматографии-сжигания/пиролиза-изотопной масс-спектрометрии применялось для оценки подлинности коричного альдегида из различных источников [70]. Для этого были исследованы коричные масла, полученные из трех разных сортов коры корицы: С. Ceylanicum, С. Cassia и С. Burmanii, а также коммерческие образцы коричного масла и образцы синтетического и натурального коричного альдегида.…”

Section: применение метода масс-спектрометрии изотопных отношений дляunclassified

Essential oils: the review of the methods for determining the authenticity and detecting adulteration

Aksenova¹,

Kuznecova²,

Vasilevskij³

et al. 2019

АиК

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Эфирные масла являются продуктами природного происхождения, которые находят самое разнообразное применение в различных областях промышленности. Высокая стоимость, трудоемкость производства и широкое использование приводят к тому, что в продаже наряду с качественными эфирными маслами часто встречают фальсифицированные. Применение поддельных масел повышает их опасность для человека, в связи с чем установление подлинности эфирных масел имеет большое значение. В обзоре проведен анализ опубликованных работ и нормативных документов, посвященных вопросам определения подлинности и выявления фальсификации эфирных масел. Рассмотрен компонентный состав эфирных масел, его вариабельность в зависимости от места произрастания эфиромасличного растения и технологии выделения масла. Обсуждены основные способы фальсификации эфирных масел и спектр используемых для этого приемов, необходимость применения соответствующих методов исследования, позволяющих контролировать подлинность продукции. Проведен анализ литературы и нормативной базы, регламентирующей качество эфирных масел, существующих методов определения их подлинности, указывают достоинства и недостатки. Особое внимание уделено методу масс-спектрометрии изотопных отношений, как наиболее перспективному, вследствие высокой точности и возможности применения для исследования практически любого типа масла. Приведены основные теоретические положения исследования стабильных изотопов и их фракционирования, принципиальные особенности методов измерения. Подтверждено широкое использование метода масс-спектрометрии изотопных отношений на практике конкретными примерами с демонстрацией новых возможностей данного метода, связанных с использованием изотопного профилирования и комбинированных методов изотопного анализа. Отмечена важность для определения подлинности масел информации об изотопном составе их компонентов, который является индикатором любых искусственных процессов, происходящих с эфирным маслом в результате фальсификации.

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Online determination of 2 H/ 1 H and 13 C/ 12 C isotope ratios of cinnamaldehyde from different sources using gas chromatography isotope ratio mass spectrometry

Cited by 23 publications

References 9 publications

Gas Chromatography‐Combustion‐Isotope Ratio Mass Spectrometry for Traceability and Authenticity in Foods and Beverages

Gas Chromatography‐Combustion‐Isotope Ratio Mass Spectrometry for Traceability and Authenticity in Foods and Beverages

N₂: a potential pitfall for bulk ²H isotope analysis of explosives and other nitrogen‐rich compounds by continuous‐flow isotope‐ratio mass spectrometry

Essential oils: the review of the methods for determining the authenticity and detecting adulteration

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Online determination of 2 H/ 1 H and 13 C/ 12 C isotope ratios of cinnamaldehyde from different sources using gas chromatography isotope ratio mass spectrometry

Cited by 23 publications

References 9 publications

Gas Chromatography‐Combustion‐Isotope Ratio Mass Spectrometry for Traceability and Authenticity in Foods and Beverages

Gas Chromatography‐Combustion‐Isotope Ratio Mass Spectrometry for Traceability and Authenticity in Foods and Beverages

N2: a potential pitfall for bulk 2H isotope analysis of explosives and other nitrogen‐rich compounds by continuous‐flow isotope‐ratio mass spectrometry

Essential oils: the review of the methods for determining the authenticity and detecting adulteration

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N₂: a potential pitfall for bulk ²H isotope analysis of explosives and other nitrogen‐rich compounds by continuous‐flow isotope‐ratio mass spectrometry