Simple ontology alignments, largely studied, link one entity of a source ontology to one entity of a target ontology. One of the limitations of these alignments is, however, their lack of expressiveness which can be overcome by complex alignments. Although different complex matching approaches have emerged in the literature, there is a lack of complex reference alignments on which these approaches can be systematically evaluated. This paper proposes two sets of complex alignments between 10 pairs of ontologies from the well-known OAEI conference simple alignment dataset. The methodology for creating the alignment sets is described and takes into account the use of the alignments for two tasks: ontology merging and query rewriting. The ontology merging alignment set contains 313 correspondences and the query rewriting one 431. We report an evaluation of state-of-the art complex matchers on the proposed alignment sets.been carried out over the last fifteen years in the context of the Ontology Alignment Evaluation Campaigns (OAEI) 1 . Even though this well-known campaign proposes a task-oriented benchmark (the OA4QA track [28]), it does not propose a complex alignment benchmark.This paper proposes two alignment sets to extend the OAEI conference track dataset [3,36] with complex alignments for two task purposes: ontology merging and query rewriting. The methodology for creating the alignment sets is described and takes into account the use of the alignments for the two targeted tasks. Here we extend the work presented in [33] and in [31] by enriching the alignment sets with new pairs of ontologies and by considering the task for which the alignment is needed. We also extend the work in [31] and by adding an evaluation of three systems [23,24,13]. We extend the evaluation of the work in [33] by adding a new system described in [13] and by evaluating all the three systems on the ten pairs of ontologies for each alignment set.The paper is organised as follows. After giving the background on ontology matching ( §2) and discussing related work ( §3), we describe the methodology to create the alignments ( §4), the alignments themselves and their use for the evaluation of approaches ( §5). We conclude with a discussion on the proposal.