In this paper the ethanol homogeneous charge compression ignition (HCCI) is achieved in a modified single cylinder engine by means of a self-developed fast thermal management system (FTMS), and the ethanol SI/HCCI operation regions are defined. It can be concluded that the thermal efficiency is higher and the NO x emission is lower in the HCCI operation region. In addition, the maximum NO x emission drops by 98%. The ethanol SI/HCCI combustion mode transition is conducted in different conditions near the SI/HCCI operation boundaries. It is likely to realize the transition by the utilization of FTMS. However, it is impossible to complete the transition within one operating cycle under current operation conditions. There are fluctuations in engine speed and brake mean effective pressure during the transition process. In order to reduce the fluctuations during the transition, the initial work concerning the effects of the spark ignition on the transition smoothness is carried out and the investigation indicates that the engine speed and brake mean effective pressure fluctuations cannot be eradicated only through spark ignition. Therefore, the control strategies combined with other factors should be further optimized.ethanol, homogeneous charge compression ignition (HCCI), combustion mode transition, spark ignition (SI), fast thermal management system (FTMS) With the advantages of high thermal efficiency and extra low NO x and soot emissions, homogeneous charge compression ignition (HCCI) combustion has become a promising combustion method and attracted much attention in internal combustion engine research all over the world since it was put forward in 1970s [1] . However, before putting this new combustion concept into practice, there are still many challenges such as ignition timing control [2] , combustion rate control [3] , limited operation region [4] and relatively high CO and HC emissions [5] , etc.When the engine operates in HCCI combustion mode, the fuel/air mixture is enriched as the engine load increases. By this, the peak in-cylinder temperature will raise, ignition will advance, and combustion rate will accelerate, so combustion phasing is hard to control. Too high combustion rate will result in the occurrence of knocking in the cylinder and this is the HCCI upper boundary. When the engine operates in light load, the peak in-cylinder temperature is a little bit lower, the lean fuel/air mixture is hard to ignite and combust and this is the HCCI lower boundary. In order to fully utilize the HCCI advantages of high thermal efficiency and extra low NO x and soot emission, it is highly recommended that the engine operates in SI with light and heavy load and transits to HCCI in medium load. In doing so, the requirement of the engine power output in heavy load can be satisfied, and the fuel consumption and emission in the medium load can be improved.The engine combustion mode transition concept between SI and HCCI was put forward by Thring [6] in 1989 with the aim of utilizing the high thermal efficiency to ...