Optical and electrical properties of copper alumina nanoparticles reinforced chlorinated polyethylene composites for optoelectronic devices

Suvarna, S.; Furhan,; Ramesan, M. T.

doi:10.1016/j.jics.2022.100772

Cited by 17 publications

(13 citation statements)

References 49 publications

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“…The direct and indirect values gradually rise by around 15% when only 1.5 wt% of FeVO 4 NPs are added to the PU/PMMA bent, as shown in Table 1. The growth of the electron‐donor nature and polymer backbone conjugation, as well as the splitting of the valence and conduction bands, are credited with this expansion of the optical energy gap 32 …”

Section: Resultsmentioning

confidence: 99%

“…The growth of the electron-donor nature and polymer backbone conjugation, as well as the splitting of the valence and conduction bands, are credited with this expansion of the optical energy gap. 32 The tail energy of Urbach E u analyzes how many localized states and the faults there are in the restricted bandgap and it can be calculated as follows:…”

Section: Study Of Optical Bandgap Energymentioning

confidence: 99%

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Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO₄ nanofiller for energy storage devices

Alghamdi,

Rajeh

2023

Polymers for Advanced Techs

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The best materials for enhanced energy storage capacitors in electrical systems are polymer nanocomposites films. Therefore, using the solution casting approach, we created a unique series of FeVO4 nanofiller‐embedded polyurethane (PU) and polymethyl methacrylate (PMMA)‐based composites. Various techniques were used to describe the prepared films. XRD spectra were used to assess the crystallinity and crystallite size of nanocomposites. The XRD spectra were used to assess the crystallinity and crystallite size of nanocomposites. With rising nanoparticles (NPs) content up to samples with 1.5 weight percent of FeVO4, XRD demonstrated an increase in the amorphous phase of the polymer mixture, which was further supported by UV–Vis measurements. FTIR was used for determining the complexation of the FeVO4 with the polymer mixture. Calculations were used to determine optical properties such as the Urbach energy and energy bandgap. With a rise in FeVO4 NP concentration, the energy bandgap decreases while the Urbach energy increases. All samples' AC conductivity spectra exhibit Jonscher's power law (JPL) behavior. Studies on dielectric permittivity and electric modulus have also been conducted in order to comprehend the charge storage characteristics and conductivity relaxation. Whereas the frequency‐dependent increase in AC electrical conductivity, the ε′ and ε″ of PU/PMMA–FeVO4 nanocomposites drop with the rising of the electric field frequency. The high level of FeVO4 was shown to improve the AC conductivity, ε′ and ε″ values of the nanocomposites. Tensile strength was improved by 38% with the addition of FeVO4 NPs into the PU/PMMA blend. Experimental outcomes show that these polymer nanocomposites materials are multifunctional and can be used as low‐permittivity nanodielectric insulators and substrates to design the next generation of flexible electronic devices and also there can be used to create a variety of advanced optoelectronic and organic electronic devices.

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Section: Resultsmentioning

confidence: 99%

Section: Study Of Optical Bandgap Energymentioning

confidence: 99%

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO₄ nanofiller for energy storage devices

Alghamdi,

Rajeh

2023

Polymers for Advanced Techs

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“…In this study, a poly(vinyl chloride) homopolymer with a K value range of 65.7-67.1 and a degree of polymerization of 1050-30 was used. According to the manufacturer's datasheet, the polymer had a bulk density of approximately 0.55 g/cm 3 with a precision of 0.02 g/cm 3 . TCI supplied the plasticizer, Bis(2-Ethylhexyl)phthalate (DEHP) (>98.0%).…”

Section: Methodsmentioning

confidence: 99%

“…TCI supplied the plasticizer, Bis(2-Ethylhexyl)phthalate (DEHP) (>98.0%). Merck provided uncoated precipitated calcium carbonate (CC) (98%) with particle sizes 50 μm and a density of 2.83 g/cm 3 . We purchased calcium stearate (>98%) from CDH.…”

Section: Methodsmentioning

confidence: 99%

“…The compatibility of PVC with numerous additives makes it an extremely versatile polymer even for making nanocomposites. [1][2][3] Specific improvements mechanical or physical attributes can be achieved by the addition of fillers in reasonable proportions. Specific inorganic fillers, such as calcium carbonate, talc, mica, and others, can be added to polymers to increase their thermal stability while also offering composite materials with better resistance to wear, hardness, and stiffness at a cheaper material costs.…”

Section: Introductionmentioning

confidence: 99%

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Exploring the synergistic effect of inorganic and organic particulates in polyvinyl chloride composites through comparative analysis and accelerated weathering

Chaturvedi,

Pappu,

Gupta

2023

Vinyl Additive Technology

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Poly(vinyl chloride) based composite materials with two distinct reinforcements, namely calcium carbonate (CC) and marble waste (MW), along with bamboo sawdust (BSD), were made through melt processing. The experimental findings revealed that the MW filled composite exhibited higher tensile strength than conventionally used CC filled composites. Composites with CC and MW have almost similar densities and MW filled composite absorbed only 0.46% more water than unfilled PVC, and CC filled composite absorbed 0.26% less water. Accelerated weathering altered composite surface, confirmed by optical microscopy and FT‐IR analysis of weathered samples revealed UV‐induced breakdown products. Composites with MW and CC fillers along with BSD in it showed less reduction in strength (5.2 and 5.8 MPa respectively) after going through accelerated weathering as compared to those with only MW (7.2 MPa) and CC (6.3 MPa) fillers. This study stablishes MW's usability as a sustainable filler in PVC composites, with comparable performance to CC, even along with cellulosic fibers.Highlights Marble waste filled composite has higher tensile strength than calcium carbonate. Both composites had similar densities and MW absorbed only ~1% more water than CC. Composite with bamboo sawdust performed slightly better after accelerated weathering. MW can be used as a sustainable filler in PVC, with comparable performance to CC.

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Synthesis, Characterization, Conductivity and Gas Sensing Application of Poly(diphenylamine)/Nickel Oxide Nanocomposites

et al. 2023

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Optical and electrical properties of copper alumina nanoparticles reinforced chlorinated polyethylene composites for optoelectronic devices

Cited by 17 publications

References 49 publications

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO₄ nanofiller for energy storage devices

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO₄ nanofiller for energy storage devices

Exploring the synergistic effect of inorganic and organic particulates in polyvinyl chloride composites through comparative analysis and accelerated weathering

Synthesis, Characterization, Conductivity and Gas Sensing Application of Poly(diphenylamine)/Nickel Oxide Nanocomposites

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Optical and electrical properties of copper alumina nanoparticles reinforced chlorinated polyethylene composites for optoelectronic devices

Cited by 17 publications

References 49 publications

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO4 nanofiller for energy storage devices

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO4 nanofiller for energy storage devices

Exploring the synergistic effect of inorganic and organic particulates in polyvinyl chloride composites through comparative analysis and accelerated weathering

Synthesis, Characterization, Conductivity and Gas Sensing Application of Poly(diphenylamine)/Nickel Oxide Nanocomposites

Contact Info

Product

Resources

About

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO₄ nanofiller for energy storage devices

Comparative analysis of the structural, optical, mechanical, and electrical properties of PMMA/PU blend‐based nanocomposites with FeVO₄ nanofiller for energy storage devices