2019
DOI: 10.1002/smtd.201900165
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Optical and Optoelectronic Properties of Black Phosphorus and Recent Photonic and Optoelectronic Applications

Abstract: The rapid development of the semiconductor industry calls for the exploration of novel semiconductors to cater to modern technical and commercial needs. Recently, black phosphorus (BP) has emerged as a new class of 2D semiconducting material and has attracted intensive research attention. The high carrier mobility and tunable direct bandgap of BP deliver great promise in photonic and optoelectronic device applications. Furthermore, the unique intrinsic anisotropy arising from the puckered structure can be expl… Show more

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Cited by 78 publications
(54 citation statements)
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References 186 publications
(405 reference statements)
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“…The advent of 2D black phosphorus (BP) offers an opportunity. First, in contrast to other 2D materials, the layered BP possesses higher molecular adsorption energy and a larger surface‐to‐volume ratio, which can maximize the adsorption effect of chemicals . In addition, BP has exceptional electrical and optoelectronic properties, such as high charge carrier mobility, a tunable direct bandgap, large on/off ratios, and anisotropic properties, which, therefore, promise high performance in various semiconductor‐based devices .…”
Section: A Comparison Of Response Time Obtained By Different Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…The advent of 2D black phosphorus (BP) offers an opportunity. First, in contrast to other 2D materials, the layered BP possesses higher molecular adsorption energy and a larger surface‐to‐volume ratio, which can maximize the adsorption effect of chemicals . In addition, BP has exceptional electrical and optoelectronic properties, such as high charge carrier mobility, a tunable direct bandgap, large on/off ratios, and anisotropic properties, which, therefore, promise high performance in various semiconductor‐based devices .…”
Section: A Comparison Of Response Time Obtained By Different Methodsmentioning
confidence: 99%
“…First, in contrast to other 2D materials, the layered BP possesses higher molecular adsorption energy and a larger surface-to-volume ratio, which can maximize the adsorption effect of chemicals. [10,11] In addition, BP has exceptional electrical and optoelectronic properties, such as high charge carrier mobility, a tunable direct bandgap, large on/off ratios, and anisotropic properties, which, therefore, promise high performance in various semiconductorbased devices. [12][13][14][15][16] To date, among the BP-based vapor/gas sensors, the most studied device configuration is field-effect transistors (FETs), in which BP acts as the FET channel.…”
mentioning
confidence: 99%
“…Black phosphorus [ 88 ] is another significant member of 2D materials (see Figure 1c), which owns a large operation range from VIS to MIR regions, bridging the wavelength gap between graphene and TMDCs. [ 89 ] Precisely, the bandgap of BP exhibits a linear increment as the number of layers decreases, which changes from 0.3 eV in bulk to 2 eV in monolayer, attributed to the electronic confinement in the vertical direction of 2D film. [ 90 ] Additionally, its bandgap can be further adjusted via chemical [ 91 ] or electrical engineering.…”
Section: D Materials and Integration Fundamentalsmentioning
confidence: 99%
“…Their extremely tunable bandgap covering infrared up to visible frequencies [ 52 ] ( Figure a), highly anisotropic electronic dispersion, [ 117 ] optical properties [ 118 ] (Figure 1b,c), and optimal surface‐to‐volume ratio render BPNSs a promising material for several electronic and optoelectronic devices, such as transistors, gas sensors, and photodetectors. [ 119 ] The in‐plane anisotropy of BPNSs provides new opportunities for novel electronic, photonic, and thermoelectric devices. The high (anisotropic) carrier mobilities and large on/off ratios at room temperature make BPNSs an excellent material for transistors, superior to graphene, which has a poor on/off ratio, and TMDs, which have low mobilities.…”
Section: Optical and Electronic Properties Of Bpns‐based Heterostructmentioning
confidence: 99%